CHEN Yi-liang,ZHU Yang-yang,XU Jun,GUO Shi-ling,ZHANG Peng-fei,HAN Li,SHANG Jian-chao
Abstract:
The hydroisomerization of n-dodecane was studied in this paper.Pt/zeolite catalysts,which respec-tively used monodimensional pore molecular seives,ZSM-22,L and SAPO-11 as support,were prepared byimpregnation method and characterized by XRD and NH3 -TPD.The influences of their acidity on hydroisomer-ization were investigated as well. The results showed that the total acid amount of the supports affect the activi-ty of the catalysts,a higher total amount of acid in the catalyst having a higher activity. The selectivity ofhydroisomerization is related to the acid strength,strong acidic centers make reaction toward the cleavage di-rection,reducing the i-dodecane selectivity; the weak acid sites conducive to the hydroisomerization of n-do-decane,and the number of weak acid sites correlated well with i-dodecane selectivity in hydroisomerization.When weak acid sites is the largest proportion in the total acid amount,the hetcrogeneous product selectivitywill be higher. This study will provide a better idea to enhance and improve catalyst acidic,which is used inthe the hydroisomerization of macromolecular paraffin.