[1]Wang Liucheng,Wu Hongqi,LI Lei,et al.Hydrolysis kinetics of hexamethyldisilazane[J].Journal of Zhengzhou University (Engineering Science),2008,29(03):85-87.[doi:10.3969/j.issn.1671-6833.2008.03.022]
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Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
29
Number of periods:
2008年03期
Page number:
85-87
Column:
Public date:
1900-01-01
- Title:
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Hydrolysis kinetics of hexamethyldisilazane
- Author(s):
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Wang Liucheng; Wu Hongqi; LI Lei; etc
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- Keywords:
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- CLC:
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- DOI:
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10.3969/j.issn.1671-6833.2008.03.022
- Abstract:
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The hydrolysis of hexamethyldisilazane at different pH values and different temperatures was investigated by gas chromatography. The results showed that the hydrolysis of hexamethyldisilinene could be described as a first-order reaction, and the hydrolysis rate decreased with the increase of pH value in the range of pH=7~pH=13. In the range of 208~308K, temperature had a significant effect on the hydrolysis rate, and the hydrolysis activation energy was 7.28 kJ·mol-81 when pH=1.