Adsorption Characteristics of 4,4′-Thiodiphenol and Bisphenol F by Activated Carbon Derived from Furfural Residue

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Adsorption Characteristics of 4,4′-Thiodiphenol and Bisphenol F by Activated Carbon Derived from Furfural Residue

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[1]LI Lin,LIU Chenglin,HAN Xiuli,et al.Adsorption Characteristics of 4,4′-Thiodiphenol and Bisphenol F by Activated Carbon Derived from Furfural Residue[J].Journal of Zhengzhou University (Engineering Science),2024,45(03):134-142.[doi:10. 13705/ j. issn. 1671-6833. 2023. 06. 004]

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Journal of Zhengzhou University (Engineering Science)[ISSN 1671-6833/CN 41-1339/T] Volume: 45 Number of periods: 2024 03 Page number: 134-142 Column: Public date: 2024-04-20

Title:: Adsorption Characteristics of 4,4′-Thiodiphenol and Bisphenol F by Activated Carbon Derived from Furfural Residue

Author(s):: LI Lin¹; LIU Chenglin¹; HAN Xiuli¹; 2; CHANG Chun¹; 2; SONG Jiande³; 1. School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China; 2. Henan Center for Outstanding Overseas Scientists, Zhengzhou University, Zhengzhou 450001, China; 3. Henan Key Laboratory of Green Manufacturing of Biobased Chemicals, Puyang 457000, China

Keywords:: adsorption; 4; 4′-thiodiphenol; bisphenol F; activated carbon; furfural residue; adsorption mechanism; thermodynamics

CLC:: X703. 1

DOI:: 10. 13705/ j. issn. 1671-6833. 2023. 06. 004

Abstract:: The activated carbon derived from furfural residue using steam activation was investigated for the adsorption 4,4′-thiodiphenol(TDP) and bisphenol F(BPF) from aqueous solution. Adsorption conditions including adsorption time, FRAC dosage, pH value, temperature and initial concentration were discussed. The results showed that adsorption equilibrium data of TDP and BPF onto FRAC were well described by the Sips and Koble-Corrigan isotherm models. Thermodynamic parameters revealed that the adsorption process of TDP and BPF on FRAC was spontaneous and exothermic process. The adsorption kinetics process of TDP and BPF conformed to the pseudo-second-order kinetic model. Besides, the adsorption of TDP and BPF on FRAC were mainly influenced by the hydrogen bonding, hydrophobic effect, electrostatic interaction and π-π interaction. At 298 K, the maximum adsorption capacities of FRAC for TDP and BPF were 5.408 3 mmol/g and 3.695 5 mmol/g, respectively, implying that the FRAC had a good application in endocrine disruptors wastewater treatment.

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