[1]ZHANG Bing,WANG Qiuru,YAO Jilei,et al.Preparation of Chitosan/Halloysite Nanotube Hybrid Porous Beads[J].Journal of Zhengzhou University (Engineering Science),2014,35(04):52-55.[doi:10.3969/j.issn.1671-6833.2014.04.013]
                                
                                Copy
                                
                                
                             
                            
                                
                                    Journal of Zhengzhou University (Engineering Science)[ISSN
                                    1671-6833/CN
                                    41-1339/T] Volume:
                                    35
                                    Number of periods:
                                    2014 04
                                    Page number:
                                    52-55
                                    Column:
                                    
                                    Public date:
                                    2014-08-30
                                
                                
                                    - Title:
 
                                    - 
                                        Preparation of Chitosan/Halloysite Nanotube Hybrid Porous Beads
 
                                
                                
                                
                                    - Author(s):
 
                                    - 
                                        ZHANG Bing; WANG Qiuru; YAO Jilei; etc;
 
                                    - 
                                        School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China
 
                                    - 
                                
 
                                
                                    - Keywords:
 
                                    - 
                                        chitosan;  halloysite nanotube;  methyl orange;  adsorption
 
                                
                                
                                    - CLC:
 
                                    - 
                                        TB383
 
                                
                                
                                    - DOI:
 
                                    - 
                                        10.3969/j.issn.1671-6833.2014.04.013
 
                                
                                
                                
                                    - Abstract:
 
                                    - 
                                        Natural resourees of halloysite nanolubes and chitosan were used to prepare CiS/HNT hybrid por.ous beads with reversed-phase cross-linking and freeze drying technique, using glutaradehyde as a cross-linkerand ’Tween80 as the emulsifier. The hybrid beads were charaeterized by seanning eleetron microseope(SEM). The SEM image shows that hybrid bead is a porous structure comprised of chitosan and aceumulatedhalloysite nanolubes. The CTS/HN’T porous beads were used as adsorbent to remove anionie dye of methyl or.ange ( MO ) from aqueous solution. The elfeet of pH , MO initial eoneentration and eontaet time were investigated. The adsorbent exhibited good stability, relatively high adsorplion eapacity and eould maintain high remov.al efficieney of above 88% afer 10 times of cyclie utilization.