[1]Wang Liucheng,Wu Hongqi,LI Lei,et al.Hydrolysis kinetics of hexamethyldisilazane[J].Journal of Zhengzhou University (Engineering Science),2008,29(03):85-87.[doi:10.3969/j.issn.1671-6833.2008.03.022]
Copy
Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
29卷
Number of periods:
2008年03期
Page number:
85-87
Column:
Public date:
1900-01-01
- Title:
-
Hydrolysis kinetics of hexamethyldisilazane
- Author(s):
-
Wang Liucheng; Wu Hongqi; LI Lei; etc
-
-
- Keywords:
-
- CLC:
-
-
- DOI:
-
10.3969/j.issn.1671-6833.2008.03.022
- Abstract:
-
The hydrolysis of hexamethyldisilazane at different pH values and different temperatures was investigated by gas chromatography. The results showed that the hydrolysis of hexamethyldisilinene could be described as a first-order reaction, and the hydrolysis rate decreased with the increase of pH value in the range of pH=7~pH=13. In the range of 208~308K, temperature had a significant effect on the hydrolysis rate, and the hydrolysis activation energy was 7.28 kJ·mol-81 when pH=1.