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Research Progress of Covalent Organic Framework Membranes for Liquid-based Separations
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[1]ZHU Junyong,CHEN Tiantian,HAN Shuangqiao,et al.Research Progress of Covalent Organic Framework Membranes for Liquid-based Separations[J].Journal of Zhengzhou University (Engineering Science),2023,44(01):13-23.[doi:10.13705/j.issn.1671-6833.2023.01.019]
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Journal of Zhengzhou University (Engineering Science)[ISSN 1671-6833/CN 41-1339/T] Volume: 44卷 Number of periods: 2023 01 Page number: 13-23 Column: Public date: 2022-12-06
Title:
Research Progress of Covalent Organic Framework Membranes for Liquid-based Separations
Author(s):
ZHU Junyong1; 2;  CHEN Tiantian1; 2;  HAN Shuangqiao1; 2;  ZHANG Yatao1; 2
1.School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China; 2.Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, Zhengzhou University, Zhengzhou 450001, China
Keywords:
covalent organic framework membrane;  liquid separation;  interfacial polymerization;  fabrication and application
CLC:
O69；TQ028. 8
DOI:
10.13705/j.issn.1671-6833.2023.01.019
Abstract:
Due to the trade-off limit between membrane flux and selectivity, the development and application of traditional polymer membranes in liquid separation are further impeded. Covalent organic frameworks (COF) are a newly emerging class of porous materials, which hold great promise for developing high-performance membranes with rapid molecule/ion transport and high-efficient liquid separations. In this review, the effects of pore size, stability, hydrophilicity/hydrophobicity and surface charge on the physicochemical properties, pore structures, and separation properties of COF structure-function relationship of COF membranes was discussed. The strategies of regulating the COF properties to optimize membrane performance were briefly described, mainly including selection/pre-design of monomers to synthesize COF membranes and post-modification of COF membranes. In addition, the fabrication strategies of advanced COF membranes were highlighted: blending, in-situ growth, vacuum-assisted filtration and interfacial polymerization. Also, the latest research advances of COF membranes in seawater desalination, sewage treatment, organic solvent nanofiltration and osmotic energy conversion were outlined. Finally, in view of membrane material preparation and commercialization requirements, the current challenges and future development trends of COF membranes were proposed, providing inspiration for the “on-demand design” of new functional COF membranes and useful guideline for the development and practical application of COF membranes for liquid separation.
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