[1]Wang Wen,Hu Haoliang,He Shitang,et al.A New Cryptophane A-coated SAW Methane Gas Sensor[J].Journal of Zhengzhou University (Engineering Science),2016,37(06):6-23.[doi:10.13705/j.issn.1671-6833.2016.03.026]
Copy
Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
37
Number of periods:
2016 06
Page number:
6-23
Column:
Public date:
2016-12-31
- Title:
-
A New Cryptophane A-coated SAW Methane Gas Sensor
- Author(s):
-
Wang Wen1; Hu Haoliang1; He Shitang1; Pan Yong2; Zhang Caihong3
-
1. Institute of Acoustics, Chinese Academy of Sciences, Beijing, 100190; 2. State Key Laboratory of National Nuclear, Biological and Chemical Disaster Protection, Institute of Chemical Defense, Beijing, 102205; 3. College of Chemistry and Chemical Engineering, Shanxi University, Taiyuan, Shanxi, 030006
-
- Keywords:
-
urface acoustic wave; methane gas sensor; cryptophane-A; resonator-oscillators
- CLC:
-
-
- DOI:
-
10.13705/j.issn.1671-6833.2016.03.026
- Abstract:
-
In view of the current situation that the traditional methane sensor technology is difficult to imple-ment the field detection and monitor on methane gas, a novel room-temperature SAW methane gas sensor coa-ted with cryptophane-A sensing interface is proposed by utilizing the supermolecular compound cryptophane-A’ s specific clathration to methane molecules. The sensor was composed of differential resonator-oscillators with excellent frequency stability, a supra-molecular CrypA coated along the acoustic propagation path, and a frequency acquisition module. The supramolecular CrypA was synthesized from vanillyl alcohol using a three-step method and deposited onto the surface of the sensing resonators via dropping method. Fast response and excellent repeatability were observed in gas sensing experiment, and the estimated detection limit and meas-ured sensitivity in gas dynamic range of 0 . 2% ~5% was evaluated as ~0 . 05 % and ~184 Hz/%, respec-tively. The measured results indicated the SAW sensor was promising for under-mine methane gas detection and monitor.