Preparation of Supported Phosphotungstic Acid Catalyst andlts Application in the Synthesis of BEA
[1]WAN Ya-zhen,LIU Ya-nan,CHEN Di.Preparation of Supported Phosphotungstic Acid Catalyst andlts Application in the Synthesis of BEA[J].Journal of Zhengzhou University (Engineering Science),2015,36(04):49-53.[doi:10.3969/j. issn.1671 -6833.2015.04.012]
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Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
36
Number of periods:
2015 04
Page number:
49-53
Column:
Public date:
2015-08-31
- Title:
- Preparation of Supported Phosphotungstic Acid Catalyst andlts Application in the Synthesis of BEA
- CLC:
- -
- DOI:
- 10.3969/j. issn.1671 -6833.2015.04.012
- Abstract:
- PTA supported catalyst was prepared by dip roasting method for the synthesis of 2-(4’ -ethyl benzoyl) benzoic acid (BEA) from phthalic anhydride and ethyl benzene as raw materials and chlorobenzene as solvent.The experimental results showed that when the load of PTA was 30%(mass fraction) and the roasting temperature was 300℃, the catalytic activity of PTA was more than doubled with SiO2 as the carrier.The effects of XRD on loading capacity and NH3-TPD on calcination temperature were analyzed. Ft-ir and BET were used to characterize PTA/SiO2 catalysts.The reuse performance of PTA/SiO2 catalyst was investigated, and the results showed that the original catalytic activity of PTA/SiO2 was still maintained after repeated use.
- References:
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[1]徐克勋.精细有机化工原料及中间体手册[M].北京:化学工业出版社,2004.[2]秦伟程.2–烷基蒽醒合成技术与应用市场[J].化工中间体﹐2004,1 ( 1 ) :10 - 13.[3]MICHEL D. Method for synthesising 2-ethylanthraqui-none : US,9628410 [ P].1996 - 9 - 19.
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