Synthesis of ε-caprolactone with Fe-Sn mixed oxide as Catalyst
[1]Zhang Yadong,Ma YongLi,Ma Jin Ling,et al.Synthesis of ε-caprolactone with Fe-Sn mixed oxide as Catalyst[J].Journal of Zhengzhou University (Engineering Science),2016,37(04):26-30.[doi:10.13705/j.issn.1671-6833.2016.04.006]
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Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
37
Number of periods:
2016 04
Page number:
26-30
Column:
Public date:
2016-08-31
- Title:
- Synthesis of ε-caprolactone with Fe-Sn mixed oxide as Catalyst
- Keywords:
- Fe-Sn-O mixed oxide; cyclohexanone; benzaldehyde; ε-caprolactone
- CLC:
- -
- DOI:
- 10.13705/j.issn.1671-6833.2016.04.006
- Abstract:
- The synthesis of ε-caprolactone from cyclohexanone was catalyzed by Fe-Sn-O composite oxides prepared by coprecipitation in molecular oxygen-benzaldehyde system, the optimum synthesis conditions were obtained as follows: 5 mmol cyclohexanone at room temperature and atmospheric pressure, N (benzaldehyde)∶ N (cyclohexanone) = 3∶1, Ethylene Dichloride 20 mL, oxygen flow rate 20 mL/min, reaction time 4 h; Reaction temperature 55 °C. Under this condition, the yield and selectivity of ε-caprolactone were 98.8% and 99.0% , respectively, and the structure of the catalyst was characterized by SEM and XRD.
- References:
- -
- Similar References:
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