[1]YUAN Si-guo,LI Xian-rui,HUANGJia-jia.Synthesis and Structural Characterization of Novel HypercrosslinkedChelating Resins Containing Sulfur[J].Journal of Zhengzhou University (Engineering Science),2011,32(06):1-4.
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Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
32
Number of periods:
2011 06
Page number:
1-4
Column:
Public date:
2011-11-10
- Title:
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Synthesis and Structural Characterization of Novel HypercrosslinkedChelating Resins Containing Sulfur
- Author(s):
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YUAN Si-guo; LI Xian-rui; HUANGJia-jia
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School of Chemical Engineering and Energy,Zhengzhou University, Zhengzhou 450001 ,China
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- Keywords:
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thiophene; sulfur heterocyclic; hypercrosslinking; chelating resin
- CLC:
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TQ415
- DOI:
-
-
- Abstract:
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A series of hypercrosslinked chelating resins containing sulfur was synthesized by the direct poly-merization of thiophene and bischloromethyl monomers or the introduction of thiophene on hypercrosslinkedresin matrix.The physicochemical structure was analyzed and characterized by elemental analysis,determina-tion of specific surface area and pore size.The results showed that the specific surface area of main chain typeresins can be up to 330.87 m’/g,after post-crosslinking,the resins were polymerized more completely , sulfurcontent and specific surface area were also improved,sulfur content (5.23 mmol/g) in the side chain typeresin was remarkably superior to the main chain type resin.This study will provide some necessary perform-ance parameters for the actual application of these functional resins in wastewater treatment, separation andconcentration of noble metals,and hydrometallurgy.