[1]LI Huiping,CHENG Kang,HAO Lingfang,et al.Synthesis of 1-(4-Methoxybenzyl)-4-hydroxymethyl-I,2,3-triazolewith Click Chemistry[J].Journal of Zhengzhou University (Engineering Science),2010,31(03):5-8.
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Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
31
Number of periods:
2010 No.03
Page number:
5-8
Column:
Public date:
2010-03-01
- Title:
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Synthesis of 1-(4-Methoxybenzyl)-4-hydroxymethyl-I,2,3-triazolewith Click Chemistry
- Author(s):
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LI Huiping; CHENG Kang; HAO Lingfang; etc
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School of Chemical Engineering and Energy,Zhengzhou University,Zhengzhou 450001,China
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- Keywords:
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proton exchange membrane; 1-(4-methoxybenzyl)-4-hydroxymethyl-1; 2; 3-triazole; click chemistry
- CLC:
-
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- DOI:
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- Abstract:
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The development of novel electrolyte membranes with dense structure,good mechanical flexibility,and high proton conductivity.but with little or no dependence on humidity at temperatures above 100℃re—mains an important challenge to the practical operation of PEMFCs.In this paper,1-(4-methoxybenzy-1)-4-hydroxymethyl-1,2,3-triazole(CTMOB),one of the proton conducting species,was synthesisedwith Click Chemistry using 4-methoxybenzyl alcohol as the starting material.The structures of systhesizedmaterials were characterized with FTIR and NMR.The results show that the proposed synthesis route of CT—MOB is feasible and the total yield of CTMOB is 38.4%.