[1]LIU Wei,HAN Runping,LIU Zan,et al.4-(2-Thiazole azo)-6-formyl-resorcinol photometric determination of lead[J].Journal of Zhengzhou University (Engineering Science),2005,26(03):12-14.[doi:10.3969/j.issn.1671-6833.2005.03.004]
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Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
26
Number of periods:
2005年03期
Page number:
12-14
Column:
Public date:
1900-01-01
- Title:
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4-(2-Thiazole azo)-6-formyl-resorcinol photometric determination of lead
- Author(s):
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LIU Wei; HAN Runping; LIU Zan; etc
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- Keywords:
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- CLC:
-
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- DOI:
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10.3969/j.issn.1671-6833.2005.03.004
- Abstract:
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The conditions for the chromogenic reaction of the new chromogen 4-(2-thiazoleazo)-6-formyl-resorcinol (TARF) with lead were studied. In the borax-hydrochloric acid buffer solution medium with pH 7.5~8.0, TARF and Pb(II.) formed a stable violet complex with a molar ratio of 1:1, the maximum absorption wavelength was 565 nm, the apparent molar absorbance coefficient was 1.62×104L/(mol·cm), and Pb(II.) complied with Bill’s law in the range of 0~3.2 μg/mL. Under the action of a certain masking agent, the reagent can be used to determine the determination of lead in the standard sample of environmental water quality.