[1]ZHOU Cairong,SUN Limin,Jiang Denggao.Study of reaction kinetics of 1,2-cyclohexanediol synthesis[J].Journal of Zhengzhou University (Engineering Science),2003,24(04):42-45.[doi:10.3969/j.issn.1671-6833.2003.04.010]
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Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
24卷
Number of periods:
2003年04期
Page number:
42-45
Column:
Public date:
1900-01-01
- Title:
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Study of reaction kinetics of 1,2-cyclohexanediol synthesis
- Author(s):
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ZHOU Cairong; SUN Limin; Jiang Denggao
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- Keywords:
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- CLC:
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- DOI:
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10.3969/j.issn.1671-6833.2003.04.010
- Abstract:
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The reaction kinetics of cyclohexene synthesis of 1,2-cyclohexanediol under the action of acidic catalyst were studied, and a kinetic model was established. Under acidic medium, hydrogen peroxide is used as oxidant for cyclohexene oxidation, the apparent kinetic equation is the first level, and the reaction formula is: rA=(dcA)/(dt)=1.594 42×105exp(-(4810.183 86)/(T)))cA, the apparent activation energy of the reaction is 39.992 kJ*mol-1, and the proposed kinetic model is experimentally verified, and the two are in good condition.