Study on the Synthesis of Cyclohexanone from Cyclohexanol Catalyzed by TEMPO
[1]ZHANG Yadong,MA Jinling.Study on the Synthesis of Cyclohexanone from Cyclohexanol Catalyzed by TEMPO[J].Journal of Zhengzhou University (Engineering Science),2015,36(06):10-.[doi:10.3969 /j.issn.1671 -6833.2015.06.003]
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Journal of Zhengzhou University (Engineering Science)[ISSN
1671-6833/CN
41-1339/T] Volume:
36卷
Number of periods:
2015 06
Page number:
10-
Column:
Public date:
2015-12-25
- Title:
- Study on the Synthesis of Cyclohexanone from Cyclohexanol Catalyzed by TEMPO
- Keywords:
- cyclohexanol; cyclohexanone; 2; 2; 6; 6-tetramethylpiperidine-1-oxyl
- CLC:
- TQ234.21
- DOI:
- 10.3969 /j.issn.1671 -6833.2015.06.003
- Abstract:
- This paper establishes a metal-free catalytic system comprising 2,2,6,6-etramethylpiperidine-l-ox-yl(TEMPO),NaClO and NaBr,catalytic oxidation of cyclohexanol to cyclohexanone. This paper studies theeffects of reaction time,pH,the dosage of the catalysts and solvent and so on. The optimum reaction condi-tions are as follows: cyclohexanol 0.3 g,TEMPO 0.005 g,NaBr 0.03 g,NaCIO 0.45 g,CH Cl,7 mL,pH9.1 and the reaction time 1 h.Three parallel experiments were performed under this condition,the averageconversition of cyclohexanol was 88.2%,and the average yield of cyclohexanone could reach 87.3%.
- References:
- -
- Similar References:
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