[1]YUAN Si-guo,LI Xian-rui,HUANGJia-jia.Synthesis and Structural Characterization of Novel HypercrosslinkedChelating Resins Containing Sulfur[J].Journal of Zhengzhou University (Engineering Science),2011,32(06):1-4.
                                
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                                    Journal of Zhengzhou University (Engineering Science)[ISSN
                                    1671-6833/CN
                                    41-1339/T] Volume:
                                    32
                                    Number of periods:
                                    2011 06
                                    Page number:
                                    1-4
                                    Column:
                                    
                                    Public date:
                                    2011-11-10
                                
                                
                                    - Title:
 
                                    - 
                                        Synthesis and Structural Characterization of Novel HypercrosslinkedChelating Resins Containing Sulfur
 
                                
                                
                                
                                    - Author(s):
 
                                    - 
                                        YUAN Si-guo; LI Xian-rui; HUANGJia-jia
 
                                    - 
                                        School of Chemical Engineering and Energy,Zhengzhou University, Zhengzhou 450001 ,China
 
                                    - 
                                
 
                                
                                    - Keywords:
 
                                    - 
                                        thiophene;  sulfur heterocyclic;  hypercrosslinking;  chelating resin
 
                                
                                
                                    - CLC:
 
                                    - 
                                        TQ415
 
                                
                                
                                    - DOI:
 
                                    - 
                                        -
 
                                
                                
                                
                                    - Abstract:
 
                                    - 
                                        A series of hypercrosslinked chelating resins containing sulfur was synthesized by the direct poly-merization of thiophene and bischloromethyl monomers or the introduction of thiophene on hypercrosslinkedresin matrix.The physicochemical structure was analyzed and characterized by elemental analysis,determina-tion of specific surface area and pore size.The results showed that the specific surface area of main chain typeresins can be up to 330.87 m’/g,after post-crosslinking,the resins were polymerized more completely , sulfurcontent and specific surface area were also improved,sulfur content (5.23 mmol/g) in the side chain typeresin was remarkably superior to the main chain type resin.This study will provide some necessary perform-ance parameters for the actual application of these functional resins in wastewater treatment, separation andconcentration of noble metals,and hydrometallurgy.