[1]李 琳,刘成林,韩秀丽,等.糠醛渣活性炭对4,4′-硫代二苯酚和双酚F 的吸附性能[J].郑州大学学报(工学版),2024,45(03):134-142.[doi:10. 13705/ j. issn. 1671-6833. 2023. 06. 004]
 LI Lin,LIU Chenglin,HAN Xiuli,et al.Adsorption Characteristics of 4,4′-Thiodiphenol and Bisphenol F by Activated Carbon Derived from Furfural Residue[J].Journal of Zhengzhou University (Engineering Science),2024,45(03):134-142.[doi:10. 13705/ j. issn. 1671-6833. 2023. 06. 004]
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糠醛渣活性炭对4,4′-硫代二苯酚和双酚F 的吸附性能()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
45
期数:
2024年03期
页码:
134-142
栏目:
出版日期:
2024-04-20

文章信息/Info

Title:
Adsorption Characteristics of 4,4′-Thiodiphenol and Bisphenol F by Activated Carbon Derived from Furfural Residue
文章编号:
1671-6833( 2024) 03-0134-09
作者:
李 琳1 刘成林1 韩秀丽12 常 春12 宋建德3
1. 郑州大学 化工学院,河南 郑州 450001;2. 郑州大学 河南省杰出外籍科学家工作室,河南 郑州 450001;3. 河南省生物基化学品绿色制造重点实验室,河南 濮阳 457000
Author(s):
LI Lin1LIU Chenglin1HAN Xiuli12CHANG Chun12SONG Jiande3
1. School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China; 2. Henan Center for Outstanding Overseas Scientists, Zhengzhou University, Zhengzhou 450001, China; 3. Henan Key Laboratory of Green Manufacturing of Biobased Chemicals, Puyang 457000, China
关键词:
吸附 44′-硫代二苯酚 双酚F 活性炭 糠醛渣 吸附机理 热力学
Keywords:
adsorption 44′-thiodiphenol bisphenol F activated carbon furfural residue adsorption mechanism thermodynamics
分类号:
X703. 1
DOI:
10. 13705/ j. issn. 1671-6833. 2023. 06. 004
文献标志码:
A
摘要:
以固废糠醛渣为原料,水蒸气活化法制备糠醛渣活性炭( FRAC) ,研究其对水体中4,4′-硫代二苯酚( TDP)和双酚F( BPF) 的吸附性能,探讨了吸附时间、FRAC 用量、pH 值、温度以及TDP 和BPF 溶液的初始浓度对吸附过程的影响。研究结果表明:Sips 和Koble-Corrigan 等温模型可以很好地描述FRAC 对TDP 和BPF 的吸附平衡数据,FRAC 对TDP 和BPF 的吸附均是自发的放热过程。FRAC 对TDP 和BPF 的吸附过程均符合准二级动力学模型。另外,TDP 和BPF 在FRAC 上的吸附主要受到氢键、疏水作用、静电作用和π—π 相互作用的共同影响。在298 K时,FRAC 吸附TDP 和BPF 的最大吸附量分别为5. 408 3 mmol/ g 和3. 695 5 mmol/ g,表明FRAC 在处理内分泌干扰物废水上具有广泛的应用前景。
Abstract:
The activated carbon derived from furfural residue using steam activation was investigated for the adsorption 4,4′-thiodiphenol(TDP) and bisphenol F(BPF) from aqueous solution. Adsorption conditions including adsorption time, FRAC dosage, pH value, temperature and initial concentration were discussed. The results showed that adsorption equilibrium data of TDP and BPF onto FRAC were well described by the Sips and Koble-Corrigan isotherm models. Thermodynamic parameters revealed that the adsorption process of TDP and BPF on FRAC was spontaneous and exothermic process. The adsorption kinetics process of TDP and BPF conformed to the pseudo-second-order kinetic model. Besides, the adsorption of TDP and BPF on FRAC were mainly influenced by the hydrogen bonding, hydrophobic effect, electrostatic interaction and π-π interaction. At 298 K, the maximum adsorption capacities of FRAC for TDP and BPF were 5.408 3 mmol/g and 3.695 5 mmol/g, respectively, implying that the FRAC had a good application in endocrine disruptors wastewater treatment.

参考文献/References:

[1] ZDARTA J, ANTECKA K, FRANKOWSKI R, et al. The effect of operational parameters on the biodegradation of bisphenols by Trametes versicolor laccase immobilized on Hippospongia communis spongin scaffolds[J]. Science of the Total Environment, 2018, 615: 784-795.

[2] GUO H, PENG L E, YAO Z K, et al. Non-polyamide based nanofiltration membranes using green metal-organic coordination complexes: implications for the removal of trace organic contaminants[J]. Environmental Science & Technology, 2019, 53(5): 2688-2694.
[3] MOUSSAVI G, POURAKBAR M, SHEKOOHIYAN S, et al. The photochemical decomposition and detoxification of bisphenol A in the VUV/ H2 O2 process: degradation, mineralization, and cytotoxicity assessment[J]. Chemical Engineering Journal, 2018, 331: 755-764.
[4] REZANIA S, CHO J, DERAKHSHAN NEJAD Z, et al. Microporous metal-organic frameworks against endocrinedisruptor bisphenol A: parametric evaluation and optimization[ J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 626: 127039.
[5] CAI J Z, ZHANG P L, KANG S J, et al. Fast and efficient adsorption of bisphenols pollutants from water by using Hydroxypropyl-β-cyclodextrin polymer[J]. Reactive and Functional Polymers, 2020, 154: 104678.
[6] MA M J, YING H J, CAO F F, et al. Adsorption of Congo red on mesoporous activated carbon prepared by CO2 physical activation[J]. Chinese Journal of Chemical Engineering, 2020, 28(4): 1069-1076.
[7] LIU C L, LIANG L L, HAN X L, et al. Optimized preparation of activated carbon from furfural residue using response surface methodology and its application for bisphenol S adsorption [ J]. Water Science and Technology, 2022, 85(3): 811-826.
[8] ACOSTA R, NABARLATZ D, SÁNCHEZ-SÁNCHEZ A, et al. Adsorption of bisphenol A on KOH-activated tyre pyrolysis char [ J]. Journal of Environmental Chemical Engineering, 2018, 6(1): 823-833.
[9] ZHANG H, SUN Y M, LI S, et al. Preparation, characterization, and efficient chromium ( Ⅵ ) adsorption of phosphoric acid activated carbon from furfural residue: an industrial waste [ J]. Water Science and Technology, 2020, 82(12): 2864-2876.
[10] SHI X X, QIAO Y Y, AN X X, et al. High-capacity adsorption of Cr(Ⅵ) by lignin-based composite: characterization, performance and mechanism[J]. International Journal of Biological Macromolecules, 2020, 159: 839-849.
[11] ZHU G Z, DENG X L, HOU M, et al. Comparative study on characterization and adsorption properties of activated carbons by phosphoric acid activation from corncob and its acid and alkaline hydrolysis residues [ J]. Fuel Processing Technology, 2016, 144: 255-261.
[12] KYZAS G Z, DELIYANNI E A, MATIS K A. Activated carbons produced by pyrolysis of waste potato peels: cobalt ions removal by adsorption[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2016, 490: 74-83.
[13] 丁雅琴. 基于4, 4′-二羟基二苯硫醚光学树脂制备及 性能[D]. 武汉: 华中科技大学,2017. DING Y Q. Preparation and property of optical resin based on 4,4′-dihydroxy diphenyl sulfide[D]. Wuhan: Huazhong University of Science and Technology, 2017.
[14] ZHU M P, ZHOU K B, SUN X D, et al. Hydrophobic N-doped porous biocarbon from dopamine for high selective adsorption of p-Xylene under humid conditions[J]. Chemical Engineering Journal, 2017, 317: 660-672.
[15] LIU L, CUI W, LU C, et al. Analyzing the adsorptive behavior of Amoxicillin on four Zr-MOFs nanoparticles: functional groups dependence of adsorption performance and mechanisms[J]. Journal of Environmental Management, 2020, 268: 110630.
[16] LIANG L L, NIU X Y, HAN X L, et al. Salt sealing induced in situ N-doped porous carbon derived from wheat bran for the removal of doxycycline from aqueous solution [ J ]. Environmental Science and Pollution Research, 2022, 29(32): 49346-49360.
[17] LV Y C, ZHANG R S, ZENG S L, et al. Removal of parsanilic acid by an amino-functionalized indium-based metal-organic framework: adsorption behavior and synergetic mechanism [ J ]. Chemical Engineering Journal, 2018, 339: 359-368.
[18] BELTRAME K K, CAZETTA A L, DE SOUZA P S C, et al. Adsorption of caffeine on mesoporous activated carbon fibers prepared from pineapple plant leaves[J]. Ecotoxicology and Environmental Safety, 2018, 147: 64-71.
[19] WU P F, CAI Z W, JIN H B, et al. Adsorption mechanisms of five bisphenol analogues on PVC microplastics[J]. Science of the Total Environment, 2019, 650: 671-678.
[20] 张迪, 杨迪, 徐翠, 等. 还原氧化石墨烯高效吸附双酚 F 的机理研究[J]. 材料导报, 2019, 33(6):954-959. ZHANG D, YANG D, XU C, et al. Study on mechanism of highly effective adsorption of bisphenol F by reduced graphene oxide[ J]. Materials Review, 2019, 33 ( 6): 954-959.

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备注/Memo

备注/Memo:
收稿日期:2023-05-06;修订日期:2023-06-13
基金项目:国家自然科学基金资助项目(22178328);河南省杰出外籍科学家工作室资助项目(GZS2022007)
通信作者:韩秀丽(1966— ),女,河南内黄人,郑州大学教授,博士,主要从事可再生能源和环境污染治理方面的研究,E-mail:xlhan@ zzu. edu. cn。
更新日期/Last Update: 2024-04-29