[1]章亚东,王自健,高晓蕾..论电子和空间效应对有机物性质和反应的影响[J].郑州大学学报(工学版),2001,22(01):14-17.[doi:10.3969/j.issn.1671-6833.2001.01.004]
　Zhang Yadong,Wang Zijian,Gao Xiaolei.On the effects of electron and spatial effects on the properties and reactions of organic matter[J].Journal of Zhengzhou University (Engineering Science),2001,22(01):14-17.[doi:10.3969/j.issn.1671-6833.2001.01.004]

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论电子和空间效应对有机物性质和反应的影响()

分享到：

《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:

22卷

期数:

2001年01期

页码:

14-17

栏目:

出版日期:

1900-01-01

文章信息/Info

Title:

On the effects of electron and spatial effects on the properties and reactions of organic matter

作者:

章亚东; 王自健; 高晓蕾.

郑州工业大学化工学院,, 郑州工业大学化工学院,, 郑州工业大学化工学院,

Author(s):

Zhang Yadong; Wang Zijian; Gao Xiaolei

关键词:

电子效应;  空间效应;  有机物性质;  反应

Keywords:

electron effect;  spatial effects;  Organic properties;  Reaction

DOI:

10.3969/j.issn.1671-6833.2001.01.004

文献标志码:

A

摘要:

对有机物分子或中间体内原子或基团间的电子效应，即诱导效应、共轭效应、超共轭效应，以及空间效应进行了研究和分析，重点探讨了上述效应对有机物或中间体稳定性，以及对亲电、亲核和自由基等类型反应取向的影响，结果表明：电子效应对有机物或中间体稳定性及反应活性有较重要的影响，空间效应亦有重要的影响，有时甚至是主要的影响因素.

Abstract:

The electron effect between atoms or groups in organic molecules or intermediates, namely induction effect, conjugation effect, superconjugation effect, and spatial effect, was studied and analyzed, focusing on the stability of organic matter or intermediate, as well as the reaction orientation of electrophilic, nucleophilic and free radicals, and the results showed that the electron effect had an important impact on the stability and reactivity of organic matter or intermediate, and the spatial effect also had an important impact, and sometimes even the main influencing factor.

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