[1]李 华,齐鹏飞,杨忠花.有机硅改性环氧NIPU防腐涂料的制备及其性能研究[J].郑州大学学报(工学版),2023,44(03):104-109.[doi:10.13705/j.issn.1671-6833.2022.06.006]
　LI Hua,QI Pengfei,YANG Zhonghua.Preparation of Organosilicon Modified Epoxy Non-isocyanate Polyurethane Anticorrosion Coating and Its Performance Test[J].Journal of Zhengzhou University (Engineering Science),2023,44(03):104-109.[doi:10.13705/j.issn.1671-6833.2022.06.006]
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有机硅改性环氧NIPU防腐涂料的制备及其性能研究()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
44
期数:
2023年03期
页码:
104-109
栏目:
出版日期:
2023-04-30

文章信息/Info

Title:
Preparation of Organosilicon Modified Epoxy Non-isocyanate Polyurethane Anticorrosion Coating and Its Performance Test
作者:
李 华1; 2;  齐鹏飞2;  杨忠花2
( 1．郑州大学 煤基生态精细化工河南省工程实验室，河南 济源 459000; 2．郑州大学 化工学院，河南 郑州 450001)

Author(s):
LI Hua1; 2; QI Pengfei2; YANG Zhonghua2
1.Henan Provincial Engineering Laboratory of Coal-based Ecological Fine Chemicals, Zhengzhou University, Jiyuan 459000, China; 2.School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China
关键词:
环氧树脂;  有机硅;  非异氰酸酯聚氨酯;  防腐;  耐盐雾性能
Keywords:
epoxy resin;  organosilicon;  non-isocyanate polyurethane;  anti-corrosion;  salt spray resistance
分类号:
TQ632. 4
DOI:
10.13705/j.issn.1671-6833.2022.06.006
文献标志码:
A
摘要:
为解决传统环氧聚氨酯涂料中异氰酸酯毒性高、固化后涂层脆性大、韧性不佳、耐化学品性和耐盐雾性能 差等问题，以有机硅改性的环氧树脂与 CO2 反应制得的环氧-环碳酸酯为树脂基料( 组分 A) ，以聚氧化丙烯二胺 ( D-230) 为固化剂基料( 组分 B) ，配以适量的填充材料和防腐助剂，制备一种新型有机硅改性环氧非异氰酸酯聚氨 酯( NIPU) 防腐涂料。采用 FTIＲ 对固化后涂层进行红外表征并对其性能进行测试。实验结果表明: 涂料在 80 ℃ 下实干时间为 20 min，外观光滑平整，无起泡、裂纹、剥落等不良现象，再经室温固化 7 d 后，涂层硬度可达到 2H， 附着力为 0 级，耐盐雾时间高达 1 500 h。所制备的有机硅改性 NIPU 防腐涂料具有良好的机械性能和防腐蚀 性能。
Abstract:
In order to solve the problems of high toxicity of isocyanate in traditional epoxy polyurethane coatings, high brittleness, poor toughness, poor chemical resistance, and salt spray resistance of the cured coating, a new type of epoxy non-isocyanate polyurethane anticorrosive coating was prepared by using epoxy-cyclocarbonate synthesized by the reaction of silicone modified epoxy resin with carbon dioxide as resin base material (component A), polypropylene oxide diamine as curing agent base material (component B), and proper fillers and auxiliaries. The cured coating was characterized by FTIR and its performance was tested. The results showed that the coating could be dried at 80 ℃ for 20 min, with a smooth appearance and no cracking, blistering or peeling, and then after curing at room temperature for seven days, the hardness could reach 2H, the adhesion was 0 grade, and the salt spray resistance time could reach 1 500 h. The prepared silicone modified NIPU anticorrosive coating had good mechanical properties and corrosion resistance.

参考文献/References:

[1] 徐子成, 毛福华, 张慧文, 等. 三氯甲基碳酸酯(三光气)的合成及其应用[J]. 上海化工, 1994(4):4-6.XU Z C, MAO F H, ZHANG H W, et al. Trichloromethylcarbonate(triphosgene) its synthesis and application[J]. Shanghai Chemical Industry, 1994(4):4-6.

[2] STACHAK P, width=11,height=11,dpi=110UKASZEWSKA I, HEBDA E, et al. Recent advances in fabrication of non-isocyanate polyurethane-based composite materials[J]. Materials, 2021, 14(13): 3497.
[3] GOMEZ-LOPEZ A, ELIZALDE F, CALVO I, et al. Trends in non-isocyanate polyurethane (NIPU) development[J]. Chemical Communications, 2021, 57(92): 12254-12265.
[4] CHEN H Y, CHAUHAN P, YAN N. “Barking” up the right tree: biorefinery from waste stream to cyclic carbonate with immobilization of CO2 for non-isocyanate polyurethanes[J]. Green Chemistry, 2020, 22(20): 6874-6888.
[5] 杨玉姿, 徐丹, 雍奇文, 等. 非异氰酸酯聚氨酯研究综述[J]. 聚氨酯工业, 2020, 35(5): 5-8.YANG Y Z, XU D, YONG Q W, et al. A review of research on non-isocyanate polyurethane[J]. Polyurethane Industry, 2020, 35(5): 5-8.
[6] 王孙博. 五元环状碳酸酯基非异氰酸酯聚氨酯的制备及性能[D]. 沈阳: 沈阳工业大学, 2020.WANG S B. Preparation and properties of non-isocyanate polyurethane based on five-membered cyclic carbonate[D]. Shenyang: Shenyang University of Technology, 2020.
[7] WU Z J, TANG L Y, DAI J T, et al. Synthesis and properties of fluorinated non-isocyanate polyurethanes coatings with good hydrophobic and oleophobic properties[J]. Journal of Coatings Technology and Research, 2019, 16(5): 1233-1241.
[8] 程原, 赵本波, 袁晓艳. 无溶剂环氧非异氰酸酯聚氨酯重防腐涂料的研制[J]. 涂料工业, 2013, 43(6): 27-31.CHENG Y, ZHAO B B, YUAN X Y. Study on solventless epoxy non-isocyanate polyurethane heavy-duty coating[J]. Paint &Coatings Industry, 2013, 43(6): 27-31.
[9] ASEMANI H, ZAREANSHAHRAKI F, MANNARI V. Design of hybrid nonisocyanate polyurethane coatings for advanced ambient temperature curing applications[J]. Journal of Applied Polymer Science, 2019, 136(13): 47266.
[10] HE X, XU X L, WAN Q, et al. Synthesis and characterization of dimmer-acid-based nonisocyanate polyurethane and epoxy resin composite[J]. Polymers, 2017, 9(12): 649.
[11] 王红凯, 李华, 李明雪, 等. 增韧耐温改性环氧树脂的制备及其表征[J]. 郑州大学学报(工学版), 2015, 36(4): 28-32.WANG H K, LI H, LI M X, et al. Preparation and characterization of heat-resistant flexible modified epoxy resin adhesive[J]. Journal of Zhengzhou University (Engineering Science), 2015, 36(4): 28-32.
[12] 林新冠, 周冰, 王成骏. 有机硅共混改性双酚A环氧树脂研究[J]. 广州化工, 2019, 47(17): 97-99.LIN X G, ZHOU B, WANG C J. Study on silicone resin blending modification of bisphenol A epoxy resin[J]. Guangzhou Chemical Industry, 2019, 47(17): 97-99.
[13] 刘贵锋, 金灿, 吴国民, 等. 有机硅改性丙三醇非异氰酸酯聚氨酯研究[J]. 热固性树脂, 2018, 33(2): 1-6.LIU G F, JIN C, WU G M, et al. Study on the silicone-modified propanetriol-based non-isocyanate polyurethanes[J]. Thermosetting Resin, 2018, 33(2): 1-6.
[14] 曾凡辉, 陈红梅, 谢续江. 水性环氧防腐涂料耐盐雾性能研究[J]. 中国涂料, 2004(12):26-28.ZENG F H, CHEN H M, XIE X J. Study on the salt-fog resistance of water-borne epoxy anticorrosive coatings[J]. China Paint, 2004(12):26-28.

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更新日期/Last Update: 2023-05-09