[1]崔铁兵,张晨,徐丽,等.萘催化氧化制备1,4-萘醌催化剂活性组分研究[J].郑州大学学报(工学版),2012,33(02):59-61.[doi:10.3969/j.issn.1671-6833.2012.02.015]
　CUI Tiebing,ZHANG Chen,XU Li.Study of Catalytic Component of Producing 1 ,4-Naphthoquinone with Catalytic Oxidation[J].Journal of Zhengzhou University (Engineering Science),2012,33(02):59-61.[doi:10.3969/j.issn.1671-6833.2012.02.015]
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萘催化氧化制备1,4-萘醌催化剂活性组分研究()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
33卷
期数:
2012年02期
页码:
59-61
栏目:
出版日期:
2012-03-10

文章信息/Info

Title:
Study of Catalytic Component of Producing 1 ,4-Naphthoquinone with Catalytic Oxidation
作者:
崔铁兵; 张晨; 徐丽; 等.
中原工学院材料与化工学院,河南郑州,450007, 河南省化工研究所有限责任公司,河南郑州,450052, 郑州大学化工与能源学院,河南郑州,450001
Author(s):
CUI Tiebing; ZHANG Chen; XU Li
1. Department of Materials and Chemistry, 2hongyuan University of Technology,Zhengzhou 450007,China; 2. Henan ChemiealIndustry Research Institute Co. Ltd. , 2hengzhou 450052,China; 3. College of Chemical Engineering, Zhengzhou UniversityZhengzhou 450001 ,China
关键词:
催化剂;  活性组分;  催化氧化;  1;  4-萘醌
Keywords:
naphehalene;  component;  air-catalytic oxidation;  1; 4-naphthoquinon
分类号:
TQ612.5
DOI:
10.3969/j.issn.1671-6833.2012.02.015
摘要:
以V2O5为主要活性组分,硅胶为载体,使用复合型催化剂,以萘的转化率、1,4-萘醌的选择性和萘醌的收率作为考核指标,通过对助催化剂进行筛选,确定SnSO4、硼酸钠等金属盐为主要助催化剂,n(K)∶n(V)=3.17时,硫酸亚锡的质量分数为1.8％,此时1,4 -萘醌收率达90％以上,选择性接近100％,碱处理后催化剂对1,4-萘醌的选择性平均提高了15％左右.
Abstract:
Using V,O, as main active component, silica gel as carrier, the cocatalyst selection was carried outby taking the conversion of the naphthalene and the selectivity of 1 ,4-naphthoquinone as criterion, it was deter.mined that $n$0, , sodium borate was main cocatalyst. Furthermore , the proper quantity of stannous sulfate added in catalyst was determined to be 1.8 96 by mass fraction at the ratio of potass to vanadium of 3. 17 in mole.Reaction based on this catalyst caused 1 ,4-naphthoquinon yield of more than 90% , and its selectivity of almost10096 . Basification of catalyst made the selectivity of 1 ,4-naphthoquinone increase by 15% on average.

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更新日期/Last Update: 1900-01-01