[1]周彩荣,王斐,高斌,等.反式-1,2-环己二醇合成新工艺的研究[J].郑州大学学报(工学版),2003,24(01):32-37.[doi:10.3969/j.issn.1671-6833.2003.01.008]
　ZHOU Cairong,Wang Fei,GAO Bin,et al.Research on a new process for the synthesis of trans-1,2-cyclohexanediol[J].Journal of Zhengzhou University (Engineering Science),2003,24(01):32-37.[doi:10.3969/j.issn.1671-6833.2003.01.008]

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反式-1,2-环己二醇合成新工艺的研究()

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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:

24

期数:

2003年01期

页码:

32-37

栏目:

出版日期:

1900-01-01

文章信息/Info

Title:

Research on a new process for the synthesis of trans-1,2-cyclohexanediol

作者:

周彩荣; 王斐; 高斌; 等.

郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002

Author(s):

ZHOU Cairong; Wang Fei; GAO Bin; etc

关键词:

反式-1;  2-环己二醇;  环己烯;  合成;  溶剂萃取;  乙酸;  乙酸酐

Keywords:

trans-1;  2-Cyclohexanediol;  Cyclohexene;  synthesis;  solvent extraction;  acetic acid;  Acetic anhydride

DOI:

10.3969/j.issn.1671-6833.2003.01.008

文献标志码:

A

摘要:

根据环己烯分子结构特点及有关单元反应的基础理论,提出了在乙酸和乙酸酐作为载氧剂的条件下,由双氧水氧化环己烯制备1,2-环己二醇的工艺路线.用正交试验法和单因素实验法考察了物料配比、反应温度、反应时间等诸多因素的影响,产物采用溶剂萃取,并利用熔点测试、红外光谱仪分析方法证实了本合成反应的产物为反式-1,2-环己二醇.

Abstract:

According to the molecular structure characteristics of cyclohexene and the basic theory of related unit reactions, a process route for the preparation of 1,2-cyclohexanediol from cyclohexene oxidation by hydrogen peroxide under the condition of acetic acid and acetic anhydride as oxygen carrier was proposed. The influence of material ratio, reaction temperature, reaction time and other factors was investigated by orthogonal test method and single factor experimental method, and the product was extracted by solvent, and the melting point test and infrared spectrometer analysis method were used to confirm that the product of the synthesis reaction was trans-1,2-cyclohexanediol.

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