[1]李铁生,吴养洁,孙雨安,等.卟啉钴配合物与含氮有机碱的加合反应研究[J].郑州大学学报(工学版),1997,18(04):78-83.
Li Tiesheng,Wu Yangjie,Sun Yuan,et al.Research on the integrated reaction of nitrogen -rich organic alkali -containing organic alkali[J].Journal of Zhengzhou University (Engineering Science),1997,18(04):78-83.
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卟啉钴配合物与含氮有机碱的加合反应研究(
)
《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]
- 卷:
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18
- 期数:
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1997年04期
- 页码:
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78-83
- 栏目:
-
- 出版日期:
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1997-07-31
文章信息/Info
- Title:
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Research on the integrated reaction of nitrogen -rich organic alkali -containing organic alkali
- 作者:
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李铁生; 吴养洁; 孙雨安; 程玉凤
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郑州工业大学化工系,郑州大学化学系,郑州轻工业学院化工系,河南省化工厅
- Author(s):
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Li Tiesheng; Wu Yangjie; Sun Yu’an; Cheng Yufeng
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Department of Chemical Engineering, Zhengzhou University of Technology, Department of Chemistry, Zhengzhou University, Department of Chemical Engineering, Zhengzhou Light Industry College, Henan Provincial Department of Chemical Engineering
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- 关键词:
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金属卟啉; 加合反应; 轴向效应
- Keywords:
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Metal glycoline; combined with reaction; axial effect
- 文献标志码:
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A
- 摘要:
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金属卟啉能与有机碱咪唑、吡啶等配合〔１〕，而单纯的卟啉却无此性质，这是由于过渡金属卟啉具有平面结构和轴向不饱合性，容易与有机碱形成加合物，增强了配体活性，提供了有利于反应的空间条件和结构条件。本文研究了一系列卟啉钴配合物与咪唑、吡啶的加合反应与紫外可见光谱的变化规律，求得了加合分子数与平衡常数。
- Abstract:
-
Metal pyrine can cooperate with organic alkaline pyriral, pyridine, etc. [1], while simple pyrine has no nature. This is because the transition metal pyrine has a plane structure and axial non -saturated. It is easy to form a combination with organic alkali, which enhances the ligand activity and provides spatial conditions and structural conditions that are conducive to response. This article studies a series of changes in the combined reaction and ultraviolet visibility spectrum of pyrodoline cobalt brackets and pyridine, and obtains the number of molecular numbers and balance constants.
更新日期/Last Update:
1900-01-01