[1]李惠萍,周彩荣,钟贤,等.氯苯定向硝化反应的研究（一）液固体系[J].郑州大学学报(工学版),1994,15(03):50-56.
　Li Huiping,Zhou Cairong,Zhong Xian,et al.Study of chloropenzene -linked to nitrification (1) The liquid solid system[J].Journal of Zhengzhou University (Engineering Science),1994,15(03):50-56.
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氯苯定向硝化反应的研究（一）液固体系()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
15
期数:
1994年03期
页码:
50-56
栏目:
出版日期:
1994-09-28

文章信息/Info

Title:
Study of chloropenzene -linked to nitrification (1) The liquid solid system
作者:
李惠萍; 周彩荣; 钟贤; 庞琰玲; 赵艳红; 戴以忠; 谢贤骅
郑州工学院，河南化工厂
Author(s):
Li Huiping;  Zhou Cairong;  Zhong Xian;  Pang Yiling;  Zhao Yanhong;  Dai Yizhong;  Xie Xianzheng
Zhengzhou Institute of Technology, Henan Chemical Plant
关键词:
氯苯; HZSM一5分子筛; 硝化; 选择性
Keywords:
Chlorine;  HZSM one 5 -molecular sieve;  nitrification;  selectivity
文献标志码:
A
摘要:
对氯苯在ＨＺＳＭ一５分子筛催化剂上的选择性硝化进行了研究，硅铝比为５８的ＨＺＳＭ一５分子筛可使对邻比达到５．３１，用正交试验法研究了各反应参数及催化剂用量对硝化反应的影响．考察了在硝化体系中不同的添加剂对于对邻比及氯苯转化率的影响，当加入某种物质时，可使对邻比达到３．０５，氯苯转化率可达３９．６５％。
Abstract:
The selective nitrification of chloropene benzene on the HJSM 5 -5 molecular sieve catalyst. The Hzm -5 -5 molecular sieve with a silicon aluminum ratio of 58 can enable the neighbor ratio to reach 5.31. The effect of the reaction parameters and the amount of catalyst on the nitrification was studied using the orthogonal test method. The effects of different additives in the nitrification system have on neighbor ratio and chlorobenzene conversion rate. When a certain substance is added, the neighbor ratio can reach 3.05, and the transformation rate of chloropenene can reach 39.65 %.
更新日期/Last Update: 1900-01-01