[1]吴晶敏,李伟杰.功能离子液体催化CO2与环氧化和物的加成反应[J].郑州大学学报(工学版),2017,38(05):71-75.[doi:10.13705/j.issn.1671-6833.2017.05.019]
　Wu Jingmin,Li Weijie.The cycloaddition reaction of CO2 catalyzed by hydroxyl and carboxyl functional ionic liquid[J].Journal of Zhengzhou University (Engineering Science),2017,38(05):71-75.[doi:10.13705/j.issn.1671-6833.2017.05.019]
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功能离子液体催化CO2与环氧化和物的加成反应()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
38
期数:
2017年05期
页码:
71-75
栏目:
出版日期:
2017-09-26

文章信息/Info

Title:
The cycloaddition reaction of CO2 catalyzed by hydroxyl and carboxyl functional ionic liquid
作者:
吴晶敏1; 李伟杰2; 3
1.鹤壁市质量技术监督检验测试中心,河南鹤壁,458030；2.郑州大学材料科学与工程学院,河南郑州450001
Author(s):
Wu Jingmin1; Li Weijie2
1. Hebi Quality Supervision, Inspection and Testing Center, Hebi, Henan, 458030; 2. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001
关键词:
离子液体; 功能化; 羟基; 羧基; 环加成反应; CO2; 环氧化合物
Keywords:
ionic liquids; functional; hydroxyl; carboxyl; cycloaddition; co2; epoxy compound
DOI:
10.13705/j.issn.1671-6833.2017.05.019
文献标志码:
A
摘要:
设计了系列羟基、羧基功能化离子液体作为催化剂催化环氧化合物与CO2的环加成反应,研究了催化剂结构与其催化性能的关系.以环氧丙烷与CO2的环加成反应为模型反应,考察了环氧丙烷与催化剂的配比、反应压强、反应温度、反应时间对合成环状碳酸酯的影响,探讨了功能化离子液体在催化过程中的可重复性.
Abstract:
A series of hydroxyl and carboxyl functionalized ionic liquids had been designed and used as catalyst for the cycloaddition reaction of CO2 with epoxy compound.Meanwhile,the relationship between catalyst structure and catalytic performance was studied.The influence of the ratio of epoxy propane and catalyst,reaction pressure,reaction temperature,reaction time on the properties of catalyst had been inspected using cycloaddition of propylene oxide and CO2 as model reaction.The repeatability of catalyst was discussed.
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