[1]章亚东,马永丽,马金玲,等.铁锡复合氧化物催化合成ε-己内酯[J].郑州大学学报(工学版),2016,37(04):26-30.[doi:10.13705/j.issn.1671-6833.2016.04.006]
Zhang Yadong,Ma YongLi,Ma Jin Ling,et al.Synthesis of ε-caprolactone with Fe-Sn mixed oxide as Catalyst[J].Journal of Zhengzhou University (Engineering Science),2016,37(04):26-30.[doi:10.13705/j.issn.1671-6833.2016.04.006]
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铁锡复合氧化物催化合成ε-己内酯()
《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]
- 卷:
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37卷
- 期数:
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2016年04期
- 页码:
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26-30
- 栏目:
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- 出版日期:
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2016-08-31
文章信息/Info
- Title:
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Synthesis of ε-caprolactone with Fe-Sn mixed oxide as Catalyst
- 作者:
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章亚东; 马永丽; 马金玲; 赵岩岩; 贾金峰
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郑州大学化工与能源学院,河南郑州,450001
- Author(s):
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School of Chemical Engineering and energy, Zhengzhou University, Zhengzhou, Henan, 450001
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- 关键词:
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Fe-Sn-O复合氧化物; 环己酮; 苯甲醛; ε-己内酯
- Keywords:
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Fe-Sn-O mixed oxide; cyclohexanone; benzaldehyde; ε-caprolactone
- DOI:
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10.13705/j.issn.1671-6833.2016.04.006
- 文献标志码:
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A
- 摘要:
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在分子氧-苯甲醛体系,由共沉淀法制备的Fe-Sn-O复合氧化物作为催化剂,催化分子氧化环己酮合成ε-己内酯,通过单因素实验,得到适宜的合成条件:常温常压下,以环己酮用量为5 mmol计;n(苯甲醛)∶n(环己酮)=3∶1;1,2-二氯乙烷20 mL;氧气流速20 mL/min;反应时间4h;反应温度55℃.该条件下,ε-己内酯收率达到98.8%,选择性达到99.0%;采用SEM、XRD等对催化剂的结构进行表征;催化剂重复使用5次仍保持较高活性.
- Abstract:
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The synthesis of ε-caprolactone from cyclohexanone was catalyzed by Fe-Sn-O composite oxides prepared by coprecipitation in molecular oxygen-benzaldehyde system, the optimum synthesis conditions were obtained as follows: 5 mmol cyclohexanone at room temperature and atmospheric pressure, N (benzaldehyde)∶ N (cyclohexanone) = 3∶1, Ethylene Dichloride 20 mL, oxygen flow rate 20 mL/min, reaction time 4 h; Reaction temperature 55 °C. Under this condition, the yield and selectivity of ε-caprolactone were 98.8% and 99.0% , respectively, and the structure of the catalyst was characterized by SEM and XRD.
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