[1]孙晓波,车宋卫,候胜利,等.溶剂萃取1,2-环己二胺的研究[J].郑州大学学报(工学版),2013,34(06):52-54,58.[doi:10.3969/j.issn.1671-6833.2013.06.013]
　TIAN Jinjun,XUE Yan,LIU Yumin.Synthesis ofandPhotocataIytic Activity for Flower-Like MicrospheresofZnONanosheets[J].Journal of Zhengzhou University (Engineering Science),2013,34(06):52-54,58.[doi:10.3969/j.issn.1671-6833.2013.06.013]
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溶剂萃取1,2-环己二胺的研究()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
34卷
期数:
2013年06期
页码:
52-54,58
栏目:
出版日期:
2013-12-30

文章信息/Info

Title:
Synthesis ofandPhotocataIytic Activity for Flower-Like MicrospheresofZnONanosheets
作者:
孙晓波; 车宋卫; 候胜利; 等.
郑州大学化工与能源学院,河南郑州,450001, 中国石油吉林石化公司炼油厂,吉林吉林,132022
Author(s):
TIAN Jin．jun1; XUE Yan1; LIU Yu—min2
1.School ofChemistry and Biological EngineeringNanyang istry and Chemical Engineering，Henan Normal University，Institute ofTechnology，Nanyang473004，China；2．SchoolofChemXinxiang453007，China
关键词:
1;  2-环己二胺;  溶剂萃取;  正丁醇
Keywords:
ZnO; hydrothermal microemulsion route; photocatalysis; Rhodamine B
分类号:
TQ236
DOI:
10.3969/j.issn.1671-6833.2013.06.013
文献标志码:
A
摘要:
选择正丁醇为萃取剂,采用溶剂萃取法研究了从稀水溶液中提取1,2-环己二胺的工艺条件,实验得到的适宜萃取工艺条件为:萃取时间60 min,萃取温度30℃,有机相与水相体积比1:1,原料液pH=12.9,1,2-环己二胺萃取率达到95％,最后,对萃取相进行减压蒸馏,得到纯度为99.86％的1,2-环己二胺.
Abstract:
ZnOwith flower·like microspheresstructures assembledby nanosheetswasprepared via the hydrothermal microemulsion route using CTAB／cyclohexane／n-hexanol／zinc acetate dehydrate as raw materials．The hierarchical ZnO microarchitecturewascharacterized by XRD，SEM and UV·vis．The results indicate that the product belongs to hexagonal ZnOwith wurtzite structure，and thediameter ofZnOmicrospheres is about5 Ixm．ZnO microspheres exhibit pore structures with high surface area of 16．5 m2·g～．The hierarchicalZnO microspheres exhibit higherphotocatalytic activity for decolorization ofRhodamineB underultraviolet irradiation than that ofcommercialZnOnanoparticles，which can be attributed to the larger surfaceareaand the spe— cial 3D structural feature of the nanosheets．

参考文献/References:

[1]李延勋,刘国际,王莹,等.多胺混合物分离提纯工艺研究[J].化学工业与工程，2009 , 26 ( 4 ):326- 330.

[2]王红专,袁伟,郭秋菊.己二胺废水的开发及应用[J].河北化工,2008,31(7):74 -75.
[3]史琳,高传柱,孙艳艳,等.手性N–单取代1 ,2-环己二胺类铂(Ⅱ)配合物的化学合成及体外抗肿瘤活性[J].药学进展,2011 ,35( 12):560 - 565.

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更新日期/Last Update: 1900-01-01