[1]孙培勤,衡明星,孙绍晖,等.泡桐直接液化固体及液相产物的红外光谱分析[J].郑州大学学报(工学版),2010,31(01):69.[doi:10.3969/j.issn.1671-6833.2010.01.016]
 SUN Peiqin,Heng Xingxing,SUN Shaohui,et al.Infrared spectroscopic analysis of direct liquefied solids and liquid phase products of Paulownia[J].Journal of Zhengzhou University (Engineering Science),2010,31(01):69.[doi:10.3969/j.issn.1671-6833.2010.01.016]
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泡桐直接液化固体及液相产物的红外光谱分析()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
31卷
期数:
2010年01期
页码:
69
栏目:
出版日期:
2010-01-30

文章信息/Info

Title:
Infrared spectroscopic analysis of direct liquefied solids and liquid phase products of Paulownia
作者:
孙培勤衡明星孙绍晖等.
郑州大学化工与能源学院,河南,郑州,450001
Author(s):
SUN Peiqin; Heng Xingxing; SUN Shaohui; etc
DOI:
10.3969/j.issn.1671-6833.2010.01.016
文献标志码:
A
摘要:
利用傅立叶变换红外光谱对泡桐以铁粉为催化剂在280~360℃去离子水中直接液化产物进行了分析,通过比较原料与残渣的红外基团差异,考察了反应温度对生物质泡桐直接液化进程及重油和轻油成分的影响.研究表明,以铁粉作为催化剂,反应温度对液化过程具有明显的影响,泡桐中的半纤维素和纤维素在320℃时反应完全;木质素从280℃开始降解,在考察的反应温度范围内,固体残渣中还包含有芳香环结构;最终液化产物重油的官能团受反应温度的影响不大;重油和轻油是复杂的混合物,含有烃、醛、酮、羧酸、酚和酯等各类化合物.
Abstract:
The direct liquefaction products of Paulownia paulownia using iron powder as catalyst in deionized water at 280~360°C were analyzed by Fourier transform infrared spectroscopy, and the effects of reaction temperature on the direct liquefaction process and heavy oil and light oil components of Paulownia biomass were investigated by comparing the infrared group differences between raw materials and residues. The results showed that with iron powder as catalyst, the reaction temperature had a significant effect on the liquefaction process, and the hemicellulose and cellulose in Paulownia were completely reacted at 320°C. Lignin degrades from 280°C, and the solid residue also contains an aromatic ring structure in the reaction temperature range. The functional group of the final liquefied product heavy oil is not greatly affected by the reaction temperature; Heavy and light oils are complex mixtures that contain various compounds such as hydrocarbons, aldehydes, ketones, carboxylic acids, phenols, and esters.

更新日期/Last Update: 1900-01-01