[1]石军,王亚明..组分玻璃化温度对共混高聚物α内耗峰的影响[J].郑州大学学报(工学版),2002,23(04):33-35.[doi:10.3969/j.issn.1671-6833.2002.04.009]
Shi Jun,Wang Yaming.Effect of component glass transition temperature on α internal consumption peak of blended polymer[J].Journal of Zhengzhou University (Engineering Science),2002,23(04):33-35.[doi:10.3969/j.issn.1671-6833.2002.04.009]
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组分玻璃化温度对共混高聚物α内耗峰的影响(
)
《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]
- 卷:
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23卷
- 期数:
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2002年04期
- 页码:
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33-35
- 栏目:
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- 出版日期:
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1900-01-01
文章信息/Info
- Title:
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Effect of component glass transition temperature on α internal consumption peak of blended polymer
- 作者:
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石军; 王亚明.
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郑州大学材料工程学院,河南,郑州,450052, 郑州大学橡塑模具国家工程研究中心,河南,郑州,450002
- Author(s):
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Shi Jun; Wang Yaming
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- 关键词:
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PEO/PMMA; SAN/PMMA; α内耗峰; 玻璃化温度
- Keywords:
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- DOI:
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10.3969/j.issn.1671-6833.2002.04.009
- 文献标志码:
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A
- 摘要:
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选择两组分玻璃化温度较远的PEO/PMMA以及玻璃化温度相近的SAN/PMMA两个均相共混体系为研究对象,考察了组分组成对共混物α内耗峰峰高、峰宽以及温频关系的影响.结果表明,共混物α内耗峰峰高及温频关系介于纯组分之间,随组分组成有规律地变化;PEO/PMMA体系的弛豫谱明显地比纯组分的宽,而SAN/PMMA体系的弛豫谱宽度跟纯组分的相差不多.认为由于PEO/PMMA两组分的玻璃化温度相差甚远,组成涨落造成玻璃化温度及弛豫时间的分布变宽,因而弛豫谱也很宽.
- Abstract:
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The effects of component composition on the relationship between peak height, peak width and temperature frequency of the blends α internal consumption of the blends were investigated. The results showed that the relationship between peak height and temperature frequency of the α internal consumption of the blend was between the pure components, and changed regularly with the composition of the components. The relaxation spectrum of the PEO/PMMA system is significantly wider than that of the pure component, while the relaxation spectrum width of the SAN/PMMA system is similar to that of the pure component. It is believed that because the glass transition temperature of the two components of PEO/PMMA is very different, the distribution of glass transition temperature and relaxation time becomes wider due to the fluctuation of composition, so the relaxation spectrum is also wide.
更新日期/Last Update:
1900-01-01