[1]郑金云,甄晓敏,李肖,等.新型磷杂菲酯类衍生物的合成及热稳定性研究[J].郑州大学学报(工学版),2013,34(02):15-20.[doi:10.3969/j.issn.1671-6833.2013.02.005]
　ZHENG Jin-yun,ZHEN Xiao-min,LI Xiao,et al.Synthesis and Thermal Stability of Novel Phosphaphenanthrene Ester Deri[J].Journal of Zhengzhou University (Engineering Science),2013,34(02):15-20.[doi:10.3969/j.issn.1671-6833.2013.02.005]
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新型磷杂菲酯类衍生物的合成及热稳定性研究()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
34
期数:
2013年02期
页码:
15-20
栏目:
出版日期:
2013-03-28

文章信息/Info

Title:
Synthesis and Thermal Stability of Novel Phosphaphenanthrene Ester Deri
作者:
郑金云1; 甄晓敏1; 李肖1; 赵玉芬1; 2
郑州大学化学与分子工程学院,河南省化学生物与有机化学重点实验室,河南郑州450001, 郑州大学化学与分子工程学院,河南省化学生物与有机化学重点实验室,河南郑州450001;厦门大学化学化工学院,福建省化学生物重点实验室,福建厦门361005
Author(s):
ZHENG Jin-yun1; ZHEN Xiao-min1; LI Xiao1; ZHAO Yu-fen1; 2
1.Key Laboratory of Chemical Biology and Organic Chemistry of Henan Province,College of Chemistry and Molecular Engineer-ing, Zhengzhou University, Zhengzhou 450052,China;2. Department of Chemistry and Key Laboratory for Chemical Biology ofFujian Province，Xiamen University，Xiamen 361005，China
关键词:
磷杂菲酯类衍生物;  合成;  热稳定性;  阻燃
Keywords:
ester derivatives of phosphaphenanthrene; synthesis; thermal stability ;  flame retardant
分类号:
O627.51
DOI:
10.3969/j.issn.1671-6833.2013.02.005
文献标志码:
A
摘要:
磷杂菲衍生物是一类重要的阻燃材料.由磷杂菲与甲醛反应得到的中间体分别与各种酰氯反应得到一系列新型的磷杂菲酯类衍生物,利用1H NMR、13C NMR、31P NMR、FT-IR、HR-MS和ESI-MS对化合物的结构做了表征.讨论了催化剂用量、物料比、溶剂、反应物浓度、反应时间及温度对反应的影响,并对反应进行优化.对代表化合物的热稳定性做了测试,结果表明这类磷杂菲酯类衍生物具有良好的热稳定性,可以作为阻燃材料使用.
Abstract:
Phosphaphenanthrene’s derivatives are an important flame retardant materials.A series of new es-ter derivatives of phosphaphenanthrene were prepared by the various acyl chlorides and the intermediate whichwas prepared by phosphaphenanthrene and formaldehyde,and their structures were characterized by 1HNMR13C NMR, 31P NMR、FT - IR\HR - MS and ESI - MS. The influences of catalyst,material ratio,sol-vent,reactants concentration,reaction time and temperature on the reaction were discussed in detail,whilethe reaction process was optimized. The thermal stabilities of the compounds were recorded,and the resultsshow that they have excellent thermal stability. The compounds are potential flame retardant materials.

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