[1]章亚东,潘开林,梁政勇..正十八硫醇的合成反应动力学研究[J].郑州大学学报(工学版),2012,33(02):44-47.[doi:10.3969/j.issn.1671-6833.2012.02.011]
　ZHANG Yadong,PAN Kailin,LIANG Zhengyong.Kinetie Study on Synthesis of n-Octadecanethiol[J].Journal of Zhengzhou University (Engineering Science),2012,33(02):44-47.[doi:10.3969/j.issn.1671-6833.2012.02.011]
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正十八硫醇的合成反应动力学研究()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
33
期数:
2012年02期
页码:
44-47
栏目:
出版日期:
2012-03-10

文章信息/Info

Title:
Kinetie Study on Synthesis of n-Octadecanethiol
作者:
章亚东; 潘开林; 梁政勇.
郑州大学化工与能源学院,河南郑州,450001, 郑州大学化工与能源学院,河南郑州,450001, 郑州大学化工与能源学院,河南郑州,450001
Author(s):
ZHANG Yadong; PAN Kailin; LIANG Zhengyong
School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China
关键词:
正十八硫醇;  氯代十八烷;  硫脲;  动力学
Keywords:
n-octadecanethiol; 1-chlorooctadecane;  thiourea;  kinetics
分类号:
TQ227.1
DOI:
10.3969/j.issn.1671-6833.2012.02.011
摘要:
以硫脲和氯代十八烷为原料合成正十八硫醇,在均相反应条件下,开展了其合成反应动力学研究,建立了第一步的反应动力学模型,测得表观反应级数为一级,化学反应动力学方程可表示为rA=-dcA/dt=4.602×1013exp(- 13 464.27/T)cA,反应的表观活化能Ea=111.95 kJ/mol,介于一般化学反应活化能40～400 kJ/mol之间,属于化学反应控制过程；并对提出的动力学模型进行了实验验证,结果表明模型可信.
Abstract:
Kineties for synthesizing n-octadecanethiol from 1-chlorooctadecane and thiourea was studied. Thereaction kinetic model of first process was investigated in the condition of homogeneous reaction, It was a firstorder reaction and the kinetics equation was written as ra= -dc /dt =4.602 x 10exp( -13 464. 27/T)CA,the activation energy was determined to be 111.95 kj/mol in the Arhenius equation, the reaction of synthesi.zing n-octadecanethiol belonged to control production of chemical reaction because the apparent activation en-ergy was in the range of 40 ~ 400 kj/mol, Finally, the kinetic model was tested and verified by experimentsThe example systems demonstrated the validity and rationality of the method.
更新日期/Last Update: 1900-01-01