[1]李本斌,赵红坤,刘国际..硫酸钠过氧化氢加合物的制备及表征[J].郑州大学学报(工学版),2004,25(02):20-22,35.[doi:10.3969/j.issn.1671-6833.2004.02.005]
　LI Benbin,Zhao Hongkun,Liu International.Preparation and characterization of sodium sulfate hydrogen peroxide adducts[J].Journal of Zhengzhou University (Engineering Science),2004,25(02):20-22,35.[doi:10.3969/j.issn.1671-6833.2004.02.005]

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硫酸钠过氧化氢加合物的制备及表征()

分享到：

《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:

25

期数:

2004年02期

页码:

20-22,35

栏目:

出版日期:

1900-01-01

文章信息/Info

Title:

Preparation and characterization of sodium sulfate hydrogen peroxide adducts

作者:

李本斌; 赵红坤; 刘国际.

中国神马集团尼龙六六盐有限责任公司,河南,平顶山,467013, 郑州大学化工学院,河南,郑州,450002

Author(s):

LI Benbin; Zhao Hongkun; Liu International

关键词:

硫酸钠;  过氧化氢;  相图;  红外光谱;  X射线衍射

Keywords:

Sodium sulfate;  hydrogen peroxide;  phase diagram;  infrared spectroscopy;  X-ray diffraction

DOI:

10.3969/j.issn.1671-6833.2004.02.005

文献标志码:

A

摘要:

对三元体系Na2SO4-H2O2-H2O的相图进行了分析,确定了合成Na2SO4·H2O·0.5H2O2适宜的原料配比.据此相图,利用质量分数为30%的双氧水制备出硫酸钠过氧化氢加合物Na2SO4·H2O·0.5H2O2,其H2O2的含量为9.48%, 接近于理论含量9.6%.利用红外光谱和X射线衍射对该加合物进行了表征.在Nicolet NEXUS 4704傅立叶红外光谱仪上测定了Na2SO4·H2O·0.5H2O2的红外光谱,在D/MAX-3B型X-射线衍射仪(RIGAKU)上测定了其X-射线粉末衍射图谱,为Na2SO4·H2O·0.5H2O2的深入研究提供了依据.

Abstract:

The phase diagram of the ternary system Na2SO4-H2O2-H2O was analyzed, and the synthetic Na2SO4· H2O·0.5H2O2 suitable raw material ratio. According to this phase diagram, sodium sulfate hydrogen peroxide adduct Na30SO2· was prepared by using hydrogen peroxide with a mass fraction of 4%. H2O·0.5H2O2, the content of H2O2 is 9.48%, which is close to the theoretical content of 9.6%. Na4704SO2· The infrared spectrum of H4O·2.0H5O2 was determined on the D/MAX-2B X-ray diffractometer (RIGAKU), and the X-ray powder diffraction pattern was determined as Na3SO2· The in-depth study of H4O·2.0H5O2 provides a basis.

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