[1]郭美圆,曹晨璐,曹春梅,等.石墨烯为载体的Pd/SnO2纳米复合材料的制备及其对CO气敏性能研究[J].郑州大学学报(工学版),2020,41(05):15-20.[doi:10.13705/j.issn.1671-6833.2019.05.021]
　Guo Meiyuan,Cao Chenlu,Cao Chunmei,et al.Synthesis of Pd Doped SnO2/ Graphene Composites and Its Gas Sensing Properties to CO[J].Journal of Zhengzhou University (Engineering Science),2020,41(05):15-20.[doi:10.13705/j.issn.1671-6833.2019.05.021]
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石墨烯为载体的Pd/SnO2纳米复合材料的制备及其对CO气敏性能研究()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
41
期数:
2020年05期
页码:
15-20
栏目:
出版日期:
2020-10-01

文章信息/Info

Title:
Synthesis of Pd Doped SnO2/ Graphene Composites and Its Gas Sensing Properties to CO
作者:
郭美圆; 曹晨璐; 曹春梅; 卢启芳; 詹自力; 高健
郑州大学化工学院,河南郑州450001

Author(s):
School of Chemical Engineering, Zhengzhou University, 450001, Zhengzhou, Henan

关键词:
Keywords:
DOI:
10.13705/j.issn.1671-6833.2019.05.021
文献标志码:
A
摘要:
采用沉淀法和超声浸渍法制备出不同石墨烯(G)载体量(G x％ )的二氧化锡(SnO 2 )复合材料,并成功负载贵金属钯(Pd)得到Pd 1.5％ /SnO 2 /G x％ ,复合材料。分析比较Pd 1.5％ /SnO 2 纳米复合材料及其石墨烯载体量分别为0.1%、0.25%、0.5%、0.75%(质量分数)的Pd 1.5％ /SnO 2 /G x％ 复合材料对CO气敏性能。结果表明:石墨烯的加入在抑制SnO2纳米颗粒团聚的同时也提高了其均匀分散程度,从而提升Pd 1.5％ /SnO 2 /G x％ 对CO的灵敏度。其中,Pd 1.5％ /SnO 2 /G 0.25％ 对CO表现出更好的传感特性。在最佳工作温度75 ℃ 下,该复合材料对115mg/m 3 CO的灵敏度值为56.2,响应时间和恢复时间分别为7s和10s,且当CO质量浓度降至5.75mg/m 3 时,该传感器仍对CO具有较好响应。
Abstract:
SnO 2 nanoparticles doped with different amounts of graphene were prepared by precipitation and ul-trasonic impregnation methods.Pd 1.5％ /SnO 2 /G x％ composites were obtained by doping Pd using the impregna-tion method. The CO sensing properties of Pd 1.5％ /SnO 2 /G x％ nanocomposites doped with graphene at different ratio of 0.1%, 0.25%, 0.5% and 0. 75% ( mass fraction) were studied. The results showed that graphene could improve the sensitivity of Pd 1.5％ /SnO 2 /G x％ , to CO by reducing the agglomeration and enhancing the dis-persion of SnO 2 , nanoparticles. So Pd 1.5％ /SnO 2 /G x％ had the excellent CO sensing properties. The optimumoperating temperature was 75 ℃ . When the CO concentration was 115 mg/m 3 , the gas response could reach 56.2 and response, recovery time was 7s and 10s, respectively. The sample Pd 1.5％ /SnO 2 /G x％ still hadgas-sensing performance when the Co concentration was only 5.75 mg/m 3 .
更新日期/Last Update: 2020-10-23