[1]张浩勤,孟晓红,邱建华,等.丙烯酰胺/对苯乙烯磺酸钠的反相微乳液聚合[J].郑州大学学报(工学版),2009,30(03):110-113.[doi:10.3969/j.issn.1671-6833.2009.03.028]
　Zhang Haoqin,Meng Xiaohong,QIU Jianhua,et al.Reversed-phase microemulsion polymerization of acrylamide/sodium p-styrenesulfonate[J].Journal of Zhengzhou University (Engineering Science),2009,30(03):110-113.[doi:10.3969/j.issn.1671-6833.2009.03.028]

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丙烯酰胺/对苯乙烯磺酸钠的反相微乳液聚合()

分享到：

《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:

30卷

期数:

2009年03期

页码:

110-113

栏目:

出版日期:

1900-01-01

文章信息/Info

Title:

Reversed-phase microemulsion polymerization of acrylamide/sodium p-styrenesulfonate

作者:

张浩勤; 孟晓红; 邱建华; 等.

郑州大学,化学工程学院,河南,郑州,450001, 郑州大学,化学工程学院,河南,郑州,450001, 郑州大学,化学工程学院,河南,郑州,450001, 郑州大学,化学工程学院,河南,郑州,450001, 郑州大学,化学工程学院,河南,郑州,450001

Author(s):

Zhang Haoqin; Meng Xiaohong; QIU Jianhua; etc

关键词:

丙烯酰胺;  对苯乙烯磺酸钠;  反相微乳液;  反相微乳液聚合

Keywords:

Acrylamide;  Sodium p-styrenesulfonate;  reversed-phase microemulsions;  Reversed-phase microemulsion polymerization

DOI:

10.3969/j.issn.1671-6833.2009.03.028

文献标志码:

A

摘要:

以非离子表面活性剂失水山梨醇单油酸酯(Span80)和聚氧乙烯失水山梨醇单油酸酯(Tween80)为复配乳化剂,环己烷为油相,以NaHSO3和(NH4)2S2O8为氧化还原引发剂,进行了丙烯酰胺(AM)/对苯乙烯磺酸钠(SSS)的反相微乳液聚合,研究了亲水-亲油平衡值(HLB)、油水比、乳化剂用量、温度和单体AM/SSS的比例对反相微乳液稳定性的影响.得出了反相微乳液的优化配方,并以该配方进行了反相微乳液聚合,得到了分子量为4×106的聚合物.聚合物的红外特征图谱表明,聚合物分子上有酰胺基和苯环、磺酸根存在.

Abstract:

The reversed-phase microemulsion polymerization of acrylamide (AM)/sodium p-styrene sulfonate (SSS) was carried out with the nonionic surfactants sorbitan monooleate (Span80) and polyoxyethylene sorbitan monooleate (Tween80) as compound emulsifiers, cyclohexane as the oil phase, and NaHSO3 and (NH4)2S2O8 as redox initiators, and the hydrophilic-lipophilic equilibrium value (HLB), oil-water ratio, emulsifier dosage, temperature and monomer AM/ Effect of SSS ratio on stability of reversed-phase microemulsions. The optimized formula of reversed-phase microemulsion was obtained, and the reversed-phase microemulsion polymerization was carried out with this formulation to obtain a polymer with a molecular weight of 4×106. The infrared characteristic map of the polymer showed that there were amide groups, benzene rings and sulfonate on the polymer molecules.

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