[1]赵建宏,李磊,武红旗,等.高效液相色谱法测定叠氮磷酸二苯酯(DPPA)的含量[J].郑州大学学报(工学版),2008,29(01):21-23.
　ZHAO Jianhong,LI Lei,Wu Hongqi,et al.Determination of diphenyl azide phosphate (DPPA) by high performance liquid chromatography[J].Journal of Zhengzhou University (Engineering Science),2008,29(01):21-23.
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高效液相色谱法测定叠氮磷酸二苯酯(DPPA)的含量()

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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

Title:: Determination of diphenyl azide phosphate (DPPA) by high performance liquid chromatography

作者:: 赵建宏; 李磊; 武红旗; 等.; 郑州大学,化工学院,河南,郑州,450001, 郑州大学,化工学院,河南,郑州,450001, 郑州大学,化工学院,河南,郑州,450001, 郑州大学,化工学院,河南,郑州,450001, 郑州大学,化工学院,河南,郑州,450001

Keywords:: High performance liquid chromatography; Diphenyl azide phosphate; Phase transfer catalysis

摘要:: 采用高效液相色谱法,紫外检测器(检测波长254 nm),在C18(150 mm × 4.6 mm i.d.)色谱柱上,以V(甲醇)∶ V(水)=70∶ 30为流动相,对由氯代磷酸二苯酯和叠氮钠为原料,相转移催化法合成的DPPA进行定量分析.结果表明,该方法的相对标准偏差为0.3 %,平均回收率99.60 %,线性相关系数为0.999 9.

Abstract:: Using high performance liquid chromatography, UV detector (detection wavelength 254 nm), at C18 (150 mm × 4.6 mm i.d.) On the column, the DPPA synthesized by phase transfer catalysis using V(methanol)∶V(water)=70∶ 30 as mobile phase was used as mobile phase. The results showed that the relative standard deviation of the method was 0.3%, the average recovery was 99.60%, and the linear correlation coefficient was 0.999 9.

[1]曹军艳,葛庆平,李娇娇,等.高效液相色谱法测定电合成反应液中的3,6-DCP和3,4,5,6-TCP[J].郑州大学学报(工学版),2012,33(06):100.[doi:10.3969/j.issn.1671-6833.2012.06.024]
[2]赵建宏,李亚芳,王建设,等.高效液相色谱法同时测定喹啉酸和喹啉[J].郑州大学学报(工学版),2013,34(04):73.[doi:10.3969/j.issn.1671-6833.2013.04.017]
[3]曹庭珠,蒋登高,王郑昌.喹诺酮类药物色谱分析中的人工神经网络技术[J].郑州大学学报(工学版),1998,19(01):60.
　[J].Journal of Zhengzhou University (Engineering Science),1998,19(01):60.

更新日期/Last Update: 1900-01-01