[1]詹予忠,周翔,胡斌,等.羟基磷酸铜的合成与表征[J].郑州大学学报(工学版),2010,31(02):79.
　ZHAN Yuzhong,ZHOU Xiang,HU Bin,et al.Synthesis and Characterization of Copper Hydroxyphosphate[J].Journal of Zhengzhou University (Engineering Science),2010,31(02):79.
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羟基磷酸铜的合成与表征()
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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
31卷
期数:
2010年02期
页码:
79
栏目:
出版日期:
2010-02-02

文章信息/Info

Title:
Synthesis and Characterization of Copper Hydroxyphosphate
作者:
詹予忠; 周翔; 胡斌; 等.
郑州大学,化工与能源学院,河南,郑州,450001, 郑州大学,化工与能源学院,河南,郑州,450001, 郑州大学,化工与能源学院,河南,郑州,450001, 郑州大学,化工与能源学院,河南,郑州,450001, 郑州大学,化工与能源学院,河南,郑州,450001
Author(s):
ZHAN Yuzhong; ZHOU Xiang; HU Bin; etc
School of Chemical and Energy Engineering，Zhengzhou University，Zhengzhou 450001，China
关键词:
均匀设计;  羟基磷酸铜;  水热合成;  对硝基苯酚;  降解
Keywords:
uniform design; copper hydroxyphosphate; hydrothermal synthesis; p-nitrophenol; degradation
文献标志码:
A
摘要:
采用均匀实验设计研究了水热法合成羟基磷酸铜,并用粉末x射线衍射分析、扫描电子显微镜、傅里叶变换红外光谱、差热-热重分析等对合成的羟基磷酸铜进行了表征.优化的合成配比为:n(乙二胺):n(磷酸):n(乙酸铜):n(水)=1.0:9.5:7.25:399,在此条件下可以稳定合成羟基磷酸铜纯相.超声预处理原料混合物可使合成时间缩短,产品粒径更均匀,合成的羟基磷酸铜具有很高的催化降解对硝基苯酚的活性.
Abstract:
The hydrothermal synthesis of copper hydroxyphosphate is studied by uniform design method．Theproduct synthesed was characterized by XRD，SEM，FTIR and TG—DTA。The optimal synthesis ratio is ethyl·enediamine／phosphoric acid／copper acetate／water(molar ratio)=1／9.5／7.25／399．Under the optimal con—dition，the pure phase of copper hydroxyphosphate can be synthesed reliably．The synthesis time is short andthe crystal size of product is uniform in the case of ultrasonic pretretament for the mixture of raw materials．Thecopper hydroxyphosphate synthesed has very high activity for the catalytic degradation of p-nitrophen01．

相似文献/References:

[1]陈江义,阳培,苏智剑..均匀设计技术在机械设计中的应用[J].郑州大学学报(工学版),2001,22(01):84.[doi:10.3969/j.issn.1671-6833.2001.01.024]
　CHEN Jiangyi,Yangpei,Su Zhijian.Application of uniform design technology in mechanical design[J].Journal of Zhengzhou University (Engineering Science),2001,22(02):84.[doi:10.3969/j.issn.1671-6833.2001.01.024]

更新日期/Last Update: 1900-01-01