[1]景国耀,韩志慧,刘国际..Na2SO4·0.5H2O2·H2O的热分解动力学研究[J].郑州大学学报(工学版),2007,28(03):101-104.[doi:10.3969/j.issn.1671-6833.2007.03.027]
　Jing Guoyao,HAN Zhihui,Liu International.Na2SO4·0.5H2O2· Thermal decomposition kinetics of H2O[J].Journal of Zhengzhou University (Engineering Science),2007,28(03):101-104.[doi:10.3969/j.issn.1671-6833.2007.03.027]

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Na2SO4·0.5H2O2·H2O的热分解动力学研究()

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《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:

28

期数:

2007年03期

页码:

101-104

栏目:

出版日期:

1900-01-01

文章信息/Info

Title:

Na2SO4·0.5H2O2· Thermal decomposition kinetics of H2O

作者:

景国耀; 韩志慧; 刘国际.

河南神马尼龙化工有限责任公司,化工一厂,河南,平顶山,467013, 郑州大学,化工学院,河南,郑州,450001

Author(s):

Jing Guoyao; HAN Zhihui; Liu International

关键词:

Na2SO4·0.5H2O2·H2O;  分解动力学;  活化能;  多元非线性回归

Keywords:

Na2SO4·0.5H2O2· H2O;  decomposition kinetics;  activation energy;  Multiple nonlinear regression

DOI:

10.3969/j.issn.1671-6833.2007.03.027

文献标志码:

A

摘要:

采用程序升温法研究Na2SO4·0.5H2O2·H2O在氮气中的热分解动力学,测定Na2SO4·0.5H2O2·H2O分解的TG-DTG和TG-DSC曲线.在8.0 K·min-1、6.1 K·min-1、4.1 K·min-1和2.0 K·min-14个升温速率下,Na2SO4·0.5H2O2·H2O的热分解是简单的一步反应,热分解温度为339.5 K.采用多元非线性回归对Na2SO4·0.5H2O2·H2O在氮气中的热分解动力学模型进行筛选,并利用主曲线法对其分解模型进行判别.Na2SO4·0.5H2O2·H2O的热分解过程受三维相界面控制,分解机理为R3机理.Na2SO4·0.5H2O2·H2O的热分解活化能为70.83 KJ·mol-1,指前因子1.96×103.

Abstract:

Na2SO4·0.5H2O2· Thermal decomposition kinetics of H2O in nitrogen, determination of Na2SO4·0.5H2O2· TG-DTG and TG-DSC curves for H2O decomposition. At 8.0 K·min-1, 6.1 K·min-1, 4.1 K·min-1 and 2.0 K·min-14 heating rates, Na2SO4·0.5H2O2· The thermal decomposition of H2O is a simple one-step reaction with a thermal decomposition temperature of 339.5 K. Multiple nonlinear regression was used to control Na2SO4·0.5H2O2· The thermal decomposition kinetic model of H2O in nitrogen was screened, and the main curve method was used to identify the decomposition model. Na2SO4·0.5H2O2· The thermal decomposition process of H2O is controlled by the three-dimensional phase interface, and the decomposition mechanism is R3 mechanism.Na2SO4·0.5H2O2· The thermal decomposition activation energy of H2O was 70.83 KJ·mol-1, which refers to the pre-factor 1.96×103.

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