[1]陈宜俍,赵俊红,李靖如,等.NaA分子筛膜的合成及其表征[J].郑州大学学报(工学版),2006,27(01):103-105128.[doi:10.3969/j.issn.1671-6833.2006.01.025]
　CHEN Yiliang,ZHAO Junhong,Li Jingru,et al.Synthesis and characterization of NaA zeolite membranes[J].Journal of Zhengzhou University (Engineering Science),2006,27(01):103-105128.[doi:10.3969/j.issn.1671-6833.2006.01.025]

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NaA分子筛膜的合成及其表征()

分享到：

《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:

27

期数:

2006年01期

页码:

103-105128

栏目:

出版日期:

1900-01-01

文章信息/Info

Title:

Synthesis and characterization of NaA zeolite membranes

作者:

陈宜俍; 赵俊红; 李靖如; 等.

郑州大学化工学院,河南,郑州,450002, 河南理工大学材料科学与工程系,河南,焦作,454000

Author(s):

CHEN Yiliang; ZHAO Junhong; Li Jingru; etc

关键词:

NaA分子筛膜;  水热法;  微波合成;  渗透气化

Keywords:

NaA molecular sieve membrane;  hydrothermal method;  microwave synthesis;  Permeation gasification

DOI:

10.3969/j.issn.1671-6833.2006.01.025

文献标志码:

A

摘要:

分别采用原位水热二次合成法、微波密闭合成法, 在管状α-Al2O3陶瓷管的外表面上合成出了一系列的NaA型分子筛膜,考察了四种原料配比、四种涂晶方法对合成分子筛膜的影响,对合成条件进行了优化. 分别采用XRD、SEM、及乙醇水溶液的渗透汽化实验(用氮气吹扫渗透侧作渗透推动力)对合成的膜进行了表征.结果表明当原料配比为Na2O∶Al2O3∶SiO2∶H2O=1∶1∶3.6∶100,清液涂晶种,微波密闭合成出的分子筛膜对水和乙醇的选择性较好,分离因子远远大于空白管的分离因子, 95%(wt)的乙醇水溶液通过膜

Abstract:

A series of NaA-type zeolite membranes were synthesized on the outer surface of tubular α-Al2O3 ceramic tubes by in-situ hydrothermal secondary synthesis and microwave closed synthesis methods, and the effects of four raw material ratios and four crystallization methods on the synthesis of zeolite membranes were investigated, and the synthesis conditions were optimized. The synthesized membranes were characterized by pervaporation experiments of XRD, SEM, and ethanol aqueous solutions (purging the permeable side with nitrogen as osmotic thrust). The results showed that when the ratio of raw materials was Na2O∶Al2O3∶SiO2∶H2O=1∶1:3.6∶100, the molecular sieve membrane synthesized by the clear liquid coating crystal seed and microwave sealing had good selectivity for water and ethanol, and the separation factor was much greater than that of the blank tube, and 95% (wt) of ethanol aqueous solution passed through the membrane

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