[1]李忠铭,陈卫航,杜金萍..有机硅/氟加入量对改性苯丙乳液的影响[J].郑州大学学报(工学版),2004,25(02):16-19.[doi:10.3969/j.issn.1671-6833.2004.02.004]
　Li Zhongming,CHEN Weihang,Du Jinping.Effect of silicone/fluorine addition on modified styrene acrylic emulsion[J].Journal of Zhengzhou University (Engineering Science),2004,25(02):16-19.[doi:10.3969/j.issn.1671-6833.2004.02.004]

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有机硅/氟加入量对改性苯丙乳液的影响()

分享到：

《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:

25

期数:

2004年02期

页码:

16-19

栏目:

出版日期:

1900-01-01

文章信息/Info

Title:

Effect of silicone/fluorine addition on modified styrene acrylic emulsion

作者:

李忠铭; 陈卫航; 杜金萍.

江汉大学化学与环境工程学院,湖北,武汉,430056, 郑州大学化工学院,河南,郑州,450002

Author(s):

Li Zhongming; CHEN Weihang; Du Jinping

关键词:

有机硅/氟;  配比;  改性单体加入量;  苯丙乳液

Keywords:

Silicone/fluorine;  Ratio;  the amount of modified monomer added;  Styrene acrylic emulsion

DOI:

10.3969/j.issn.1671-6833.2004.02.004

文献标志码:

A

摘要:

用八甲基环四硅氧烷、乙烯基环四硅氧烷、三氟乙酸丙烯酯共同对苯丙乳液进行改性,确定了适宜的改性单体加入量及有机硅/氟配比.乳液的红外光谱显示,得到了有机硅/氟改性苯丙乳液.研究了有机硅、氟的加入量对聚合体系稳定性、乳液涂膜性能、反应速度的影响.结果表明,随着改性单体含量的增加,反应速度有所降低;当控制体系中改性单体质量分数≤15%时,八甲基环四硅氧烷、乙烯基环四硅氧烷、三氟乙酸丙烯酯配比对乳液稳定性没有影响.

Abstract:

The phenylene acrylic emulsion was modified with octamethylcyclotetrasiloxane, vinyl cyclotetrasiloxane and propylene trifluoroacetate, and the appropriate amount of modified monomer and the silicone/fluorine ratio were determined. The infrared spectrum of the emulsion showed that the silicone/fluorine-modified styrene acrylic emulsion was obtained. The effects of silicone and fluorine on the stability of polymerization system, the performance of emulsion coating film and reaction speed were studied. The results showed that with the increase of the content of modified monomers, the reaction speed decreased. When the mass fraction of modified monomer in the control system ≤15%, the ratio of octamethylcyclotetrasiloxane, vinyl cyclotetrasiloxane and propylene trifluoroacetate had no effect on the stability of the emulsion.

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