[1]章亚东,高晓蕾,蒋登高,等.聚乙二醇相转移催化合成对硝基苯甲醚工艺[J].郑州大学学报(工学版),2002,23(02):23-26.[doi:10.3969/j.issn.1671-6833.2002.02.007]
　Zhang Yadong,Gao Xiaolei,Jiang Denggao,et al.Polyethylene glycol phase transfer catalyzed synthesis of p-nitroanisole process[J].Journal of Zhengzhou University (Engineering Science),2002,23(02):23-26.[doi:10.3969/j.issn.1671-6833.2002.02.007]
点击复制

聚乙二醇相转移催化合成对硝基苯甲醚工艺()
分享到：

《郑州大学学报(工学版)》[ISSN:1671-6833/CN:41-1339/T]

卷:
23
期数:
2002年02期
页码:
23-26
栏目:
出版日期:
1900-01-01

文章信息/Info

Title:
Polyethylene glycol phase transfer catalyzed synthesis of p-nitroanisole process
作者:
章亚东; 高晓蕾; 蒋登高; 等.
郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002, 郑州大学化工学院,河南,郑州,450002
Author(s):
Zhang Yadong; Gao Xiaolei; Jiang Denggao; etc
关键词:
相转移催化;  合成;  对硝基苯甲醚;  聚乙二醇
Keywords:
DOI:
10.3969/j.issn.1671-6833.2002.02.007
文献标志码:
A
摘要:
研究了不同分子量聚乙二醇(PEG)作为相转移催化剂由对硝基氯苯合成对硝基苯甲醚工艺,探讨了聚乙二醇分子量、分子结构中聚氧乙烯(-OCH2CH2-)单元链节数量(亦称平均聚合度)等对反应速率的影响,考察了氢氧化钠、催化剂浓度和用量等对反应的影响,阐述了PEG相转移催化反应机理,建立了PEG相转移催化条件下合成对硝基苯甲醚的适宜工艺条件,即温度78～80 ℃,n(PCNB)∶n(CH3OH)∶n(NaOH)∶n(P EG-400)=1∶3∶3∶(0.025～0.05),反应时间约7～8 h.此外,还测定了该条
Abstract:
The synthesis of p-nitroanisole from p-nitrochlorobenzene from p-nitrochlorobenzene with different molecular weights polyethylene glycol (PEG) as a phase transfer catalyst was studied, the effects of polyethylene glycol molecular weight and the number of polyoxyethylene (-OCH2CH2-) unit links (also known as average polymerization) in the molecular structure on the reaction rate were investigated, the effects of sodium hydroxide, catalyst concentration and dosage on the reaction were investigated, and the catalytic reaction mechanism of PEG phase transfer was elaborated. A suitable process condition for the synthesis of p-nitroanisole under the catalytic condition of PEG phase transfer was established, that is, the temperature was 78~80 °C, n(PCNB)∶n(CH3OH)∶n(NaOH)∶n(P EG-400)=1∶3∶3∶(0.025~0.05), and the reaction time was about 7~8 h

相似文献/References:

[1]王留成,王文天,赵建宏,等.不对称双季铵盐表面活性剂的合成[J].郑州大学学报(工学版),2010,31(03):9.
　WANG Liucheng,WANG Wentian,ZHAO Jianhong,et al.Synthesis of Dissymmetric Bis-quaternary Ammonium Salt Surfactant[J].Journal of Zhengzhou University (Engineering Science),2010,31(02):9.
[2]石晓华,刘娜,熊冕,等.羟基特戊酸新戊二醇二丙烯酸酯(HPHPDA)的合成及性能研究[J].郑州大学学报(工学版),2013,34(02):4.[doi:10.3969/j.issn.1671-6833.2013.02.002]
　SHI Xiao-hua,LIU Na,XIONG Mian,et al.Synthesis and Properties of 3-hydroxypivalic Acid Neopentylglycol Diacrylate ( HPHPDA)[J].Journal of Zhengzhou University (Engineering Science),2013,34(02):4.[doi:10.3969/j.issn.1671-6833.2013.02.002]
[3]郑金云,甄晓敏,李肖,等.新型磷杂菲酯类衍生物的合成及热稳定性研究[J].郑州大学学报(工学版),2013,34(02):15.[doi:10.3969/j.issn.1671-6833.2013.02.005]
　ZHENG Jin-yun,ZHEN Xiao-min,LI Xiao,et al.Synthesis and Thermal Stability of Novel Phosphaphenanthrene Ester Deri[J].Journal of Zhengzhou University (Engineering Science),2013,34(02):15.[doi:10.3969/j.issn.1671-6833.2013.02.005]
[4]王留成,张磊,赵建宏,等.2-氨基偶氮甲苯催化加氢合成2,5-二氨基甲苯[J].郑州大学学报(工学版),2013,34(02):21.[doi:10.3969/j. issn.1671-6833.2013.00.006]
　WANG Liu-cheng,ZHANG Lei,ZHAO Jian-hong,et al.Research on the Preparation of 2 ,5-diaminotoluenewith 2-aminoazotoluene Catalytic Hydrogenation[J].Journal of Zhengzhou University (Engineering Science),2013,34(02):21.[doi:10.3969/j. issn.1671-6833.2013.00.006]
[5]李群,杨蕊,赵昔慧..逐滴一步反应法合成L-赖氨酸缩香兰素席夫碱铜配合物及其表征[J].郑州大学学报(工学版),2008,29(02):120.[doi:10.3969/j.issn.1671-6833.2008.02.031]
　Li Qun,Yang Rui,Zhao Xihui.Synthesis of L-lysine vanillin Schiff base copper complex by drop-by-drop reaction and its characterization[J].Journal of Zhengzhou University (Engineering Science),2008,29(02):120.[doi:10.3969/j.issn.1671-6833.2008.02.031]
[6]李雯,赵君颖,章亚冬,等.一水合-L-(2R,3R)-(-)-二苯甲酰酒石酸的合成[J].郑州大学学报(工学版),2006,27(02):62.[doi:10.3969/j.issn.1671-6833.2006.02.015]
　LI Wen,ZHAO Junying,Zhang Yadong,et al.Synthesis of -L-(2R,3R)-(-)-dibenzoyl tartaric acid monohydrate[J].Journal of Zhengzhou University (Engineering Science),2006,27(02):62.[doi:10.3969/j.issn.1671-6833.2006.02.015]
[7]闫学斌,李雯,刘宏民..Lasiokaurin的合成与活性研究[J].郑州大学学报(工学版),2006,27(03):113.[doi:10.3969/j.issn.1671-6833.2006.03.028]
[8]孙晓波,任珂,栾向海,等.磷钨酸催化合成戊二酸二丁酯的研究[J].郑州大学学报(工学版),2006,27(04):36.[doi:10.3969/j.issn.1671-6833.2006.04.010]
[9]李雯,尤启冬..2-氨基-3-三氟甲基苯甲酸的合成[J].郑州大学学报(工学版),2004,25(03):29.[doi:10.3969/j.issn.1671-6833.2004.03.008]
　LI Wen,You Qidong.Synthesis of 2-amino-3-(trifluoromethyl)benzoic acid[J].Journal of Zhengzhou University (Engineering Science),2004,25(02):29.[doi:10.3969/j.issn.1671-6833.2004.03.008]
[10]周彩荣,王斐,高斌,等.反式-1,2-环己二醇合成新工艺的研究[J].郑州大学学报(工学版),2003,24(01):32.[doi:10.3969/j.issn.1671-6833.2003.01.008]
　ZHOU Cairong,Wang Fei,GAO Bin,et al.Research on a new process for the synthesis of trans-1,2-cyclohexanediol[J].Journal of Zhengzhou University (Engineering Science),2003,24(02):32.[doi:10.3969/j.issn.1671-6833.2003.01.008]

更新日期/Last Update: 1900-01-01